Fluidized Bed Methane Synthesis from Wood Gasification

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Solution Overview

Problem

Current processes for synthesizing methane from wood gasification produce inefficient results due to the presence of aromatic hydrocarbons and other impurities, which require costly purification steps and reduce overall efficiency.

Innovation Solution

A process using a fluidized bed catalyst with nickel or nickel compounds supported on ceramic carriers to convert hydrogen and carbon monoxide into methane, allowing simultaneous endothermic reforming of higher hydrocarbons and exothermic methane generation, thereby enhancing thermal efficiency and reducing the need for extensive purification.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional fixed-bed catalyst processes are used for methane synthesis from wood gasification, then the process requires extensive purification of aromatic hydrocarbons and other impurities, but this increases process complexity and costs

Engineering Contradiction:
Improvemethane synthesis efficiencyVSAvoidpurification process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies this principle by allowing aromatic hydrocarbons and other impurities from wood gasification to remain in the feed gas, converting them into beneficial products through in-situ catalytic reforming in the fluidized bed reactor. The Ni-based catalyst transforms these harmful impurities into additional methane and other valuable hydrocarbons, eliminating the need for costly purification steps while actually improving overall process efficiency and methane yield.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Reliability

If extensive purification steps are implemented to remove aromatic hydrocarbons, ammonia, and hydrogen sulfide, then catalyst deactivation is reduced, but production costs increase significantly

Engineering Contradiction:
Improvecatalyst activity stabilityVSAvoidprocess cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent implements self-service by designing a fluidized bed reactor system where the Ni-based catalyst continuously reformes aromatic hydrocarbons and impurities into methane in-situ. The system automatically manages the conversion of potential deactivating substances into useful products, maintaining catalyst activity without requiring external purification interventions. The fluidized bed configuration ensures continuous catalyst regeneration and prevents coking, allowing the process to be economically viable.

Inventive Principle:
Principle #25Self-service

3Productivity

If conventional catalytic processes are used without fluidized bed technology, then equipment simplicity is maintained, but catalyst deactivation occurs rapidly reducing productivity

Engineering Contradiction:
Improvemethane generation rateVSAvoidcatalyst lifetime
Core Design Contradiction:
ProductivityVSDuration of action of moving object

Solution Approach 1:

The patent applies dynamics by transitioning from a static fixed-bed catalyst system to a dynamic fluidized bed system. The catalyst particles are suspended and continuously circulated in the fluidized bed, allowing constant contact with the feed gas and products. This dynamic configuration enables continuous catalyst regeneration, prevents localized hot spots and coking, and maintains high catalytic activity over extended periods, thereby significantly improving both productivity and catalyst lifetime.

Inventive Principle:
Principle #15Dynamics

4Reliability

If aromatic hydrocarbons are completely removed from the feed gas, then catalyst poisoning is prevented, but energy efficiency and process economics deteriorate

Engineering Contradiction:
Improvecatalyst performanceVSAvoidenergy efficiency
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent converts the previously harmful aromatic hydrocarbons into a beneficial resource by using the Ni-based fluidized bed catalyst to reform them in-situ into additional methane and other hydrocarbons. This approach not only prevents catalyst poisoning through continuous reforming but also improves energy efficiency by utilizing the chemical energy contained in the aromatic compounds rather than discarding them through purification steps.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach maintains catalyst activity and selectivity, achieving high methane yield and complete conversion of higher hydrocarbons without deactivation, even when operating continuously, and reduces the costs associated with purification steps.

Implementation Method 1

bringing the feed gas mixture in contact with a fluidized bed catalyst having catalyst particles which comprise as catalytic active component a metal and/or a metal compound

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

Both thermo-chemical reactions, the endothermic reformation of higher hydrocarbons, i.e. aromatic hydrocarbons, and the exothermic methane generation, proceed simulataneously within the fluidized bed catalytic reactor

Methodology Applied
Scientific EffectEndothermic reaction: Endothermic Reaction

Implementation Method 3

Both thermo-chemical reactions, the endothermic reformation of higher hydrocarbons, i.e. aromatic hydrocarbons, and the exothermic methane generation, proceed simulataneously within the fluidized bed catalytic reactor

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Implementation Method 4

Using a fluidized bed catalytic reactor avoids a rapid deactivation of the catalyst material and therefore delivers a high activity of the catalytic active components in the process

Methodology Applied
Scientific EffectFluidisation: Fluidisation

Data Source

PatentUS8313544B2Process for the synthetic generation of methane
Publication Date: 2012.11.20 PAUL SCHERRER INSTITUT
  • US8313544B2 patent drawing
  • US8313544B2 patent drawing
  • US8313544B2 patent drawing

AI summary

In a process for the synthetic generation of methane from a feed gas mixture, a feed gas mixture including carbon monoxide, hydrogen, water vapor, CO2, volatile hydrocarbons comprising C2 and higher, unsaturated C2 components and aromatic hydrocarbons in the range of 1 to 10 vol % is provided. The feed gas mixture is contacted with a fluidized bed catalyst having catalyst particles having a catalytic active component selected from the group consisting of a metal, a metal compound and combinations thereof. The contacting occurs at an elevated temperature in the range of 250 to 450° C., a feed gas pressure in the range of 0.8 to 70 bar, a gas hourly space velocity of 1000 to 50000 h−1, and a concentration of H2/CO in the gas mixture in the range of 0.25 to 5.