Fluidized Bed Reactor Sulfur Capture Composite Fuel

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Solution Overview

Problem

Conventional gasification reactors face inefficiencies in combustion and emission control, particularly in managing sulfur compounds and maintaining stable fluidized-bed operations, which affect the overall efficiency and environmental impact of power generation.

Innovation Solution

A reactor system with a fluidized bed of inert particles and a heat exchanger that uses a solid fuel composite with a sorbent like calcium carbonate to absorb sulfur compounds, combined with a multi-stage reactor design and specific heat-exchanging configurations to optimize combustion and heat transfer, allowing for efficient operation and zero-emission gas production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional gasification reactors combust carbonaceous fuel with oxidizer, then electrical power is generated, but sulfur compounds are emitted and combustion efficiency is reduced

Engineering Contradiction:
Improvepower generation efficiencyVSAvoidsulfur compound emissions
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

A sorbent material (such as calcium carbonate or other sulfur-removing agents) is introduced as an intermediary substance into the fluidized bed reactor. This sorbent chemically interacts with sulfur compounds formed during combustion, converting them into solid sulfates that can be easily separated from the gas stream, thereby reducing sulfur emissions while maintaining power generation efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The reactor employs a composite fuel structure combining carbonaceous fuel particles with sorbent materials in a fluidized bed configuration. This composite approach allows simultaneous combustion for power generation and sulfur removal, as the sorbent is distributed throughout the fuel bed and reacts with sulfur compounds during the combustion process

Inventive Principle:
Principle #40Composite materials

2Productivity

If fluidized bed combustion is used for efficient burning, then combustion efficiency improves, but mechanical wear increases

Engineering Contradiction:
Improvecombustion efficiencyVSAvoidmechanical wear resistance
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The reactor operates by carefully controlling fluidization parameters such as gas velocity, particle size distribution, and bed density to maintain optimal combustion efficiency while minimizing excessive particle agitation that causes mechanical wear. The fluidized bed is designed to provide sufficient mixing and heat transfer without excessive mechanical stress on components

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If sulfur removal additives are added to fuel, then emissions are reduced, but combustion stability becomes difficult to maintain

Engineering Contradiction:
Improveemission reductionVSAvoidcombustion stability
Core Design Contradiction:
Object-generated harmful factorsVSStability of the object's composition

Solution Approach 1:

The sorbent material is strategically distributed throughout the fluidized bed in specific local concentrations optimized for sulfur capture while maintaining overall combustion stability. Different regions of the fluidized bed may have varying sorbent loadings, with higher concentrations in zones where sulfur compounds are most prevalent, allowing effective sulfur removal without compromising combustion stability

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves efficient combustion, reduces mechanical wear, and minimizes emissions by uniformly dispersing reactants and absorbing sulfur compounds, thereby enhancing power generation efficiency and environmental sustainability.

Implementation Method 1

using a solid fuel composite with a sorbent like calcium carbonate to absorb sulfur compounds

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

a heat exchanger that uses a solid fuel composite with a sorbent like calcium carbonate to absorb sulfur compounds, combined with a multi-stage reactor design and specific heat-exchanging configurations to optimize combustion and heat transfer

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Implementation Method 3

A reactor system with a fluidized bed of inert particles

Methodology Applied
Scientific EffectFluidization: Fluidisation

Data Source

PatentUS9803512B2Reactor system and solid fuel composite therefor
Publication Date: 2017.10.31 GAS TECH INST
  • US9803512B2 patent drawing
  • US9803512B2 patent drawing
  • US9803512B2 patent drawing

AI summary

A reactor system includes a fluidized-bed. A fuel and a sulfur absorbent material are eluted through the fluidized-bed. The reactor system may include a heat exchanger having a heat-exchanging portion within a heating zone of the reactor that is hermetically sealed from the heating zone. The reactor may include loose particles of an inert bed material for forming the fluidized-bed. A feed system may be provided to inject a solid fuel composite that includes a mixture of a solid, carbonaceous fuel and a solid reagent into the reactor.