Preparation and Application of Light-resistant Fluorane Chromotropic Dye

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Fluorane chromotropic dyes exhibit poor light resistance, leading to color fading when exposed to sunlight, limiting their application in outdoor and long-term use.

Innovation Solution

A fluorane chromotropic dye with an optimized molecular structure incorporating alkylamino groups is designed to enhance light resistance, featuring specific alkyl chains and polar groups, which improves the dye's agglomeration state and resistance to sunlight exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If fluorane chromotropic dyes are used for their multiple response characteristics, then they can be widely applied in smart textiles and sensors, but they exhibit poor light resistance and lose color rendering ability after sunlight exposure

Engineering Contradiction:
Improvemultiple response characteristicsVSAvoidlight resistance
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent modifies the molecular structure parameters of fluorane chromotropic dyes by introducing specific substituents (alkyl chains, polar groups, alkylamino groups) to change the chemical composition and spatial arrangement, thereby improving light resistance while preserving the multiple response characteristics needed for smart textile applications

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite molecular structures by combining fluorane chromotropic dye cores with various functional groups (alkyl chains, polar groups, alkylamino groups) to form enhanced dye molecules that exhibit both the desired responsiveness and improved light resistance, effectively creating a composite material at the molecular level

Inventive Principle:
Principle #40Composite materials

2Reliability

If ultraviolet absorbers are introduced into thermochromic microcapsule shells or smart textile surfaces, then light resistance is improved, but the complexity of the system increases

Engineering Contradiction:
Improvelight resistanceVSAvoidsystem complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the functions of the chromotropic dye and ultraviolet protection by incorporating UV-absorbing structural features directly into the dye molecule itself, eliminating the need for separate UV absorber components and reducing system complexity while maintaining light resistance

Inventive Principle:
Principle #5Merging (Combining)

3Reliability

If molecular structures of fluorane chromotropic dyes are optimized and designed, then light resistance is improved, but the difficulty of synthesis and manufacturing increases

Engineering Contradiction:
Improvelight resistanceVSAvoidsynthesis difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent segments the molecular design into modular components (core fluorane chromotropic structure, alkyl chain substituents, polar group substituents, alkylamino groups) that can be systematically combined and synthesized through standardized chemical reactions, making the complex molecular optimization more manageable and manufacturable

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS20240425703A1Preparation and Application of Light-resistant Fluorane Chromotropic Dye
Publication Date: 2024.12.26 JIANGNAN UNIV
  • US20240425703A1 patent drawing
  • US20240425703A1 patent drawing
  • US20240425703A1 patent drawing

AI summary

The present disclosure discloses preparation and application of a light-resistant fluorane chromotropic dye and belongs to the technical field of fine chemical engineering. By optimizing a structure of a commercial fluorane dye, the present disclosure provides a preparation method for a fluorane dye with a full spectrum and good light resistance. On the basis of maintaining a color rendering property, discoloration sensitivity, discoloration fatigue resistance and other properties of the dye, the light resistance is improved, a light resistance time is prolonged by 8-28 hours and is increased by 50% to 80%, a main problem of application of such temperature-sensitive materials in the field of functional textiles is solved, the application field is expanded, and economic benefits are facilitated.