Fluorescent Binder for Additive Manufacturing Monitoring

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional binders in additive manufacturing do not provide sufficient visual contrast for reliable optical monitoring of binder deposition, quantity, and cure extent, leading to issues with print quality and geometry.

Innovation Solution

A binder solution comprising a linkable thermoplastic binder, a fluorescent material encapsulated to prevent quenching, and a binder medium that fluoresces under electromagnetic radiation, allowing for optical monitoring of binder deposition and cure status.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional binders are used in additive manufacturing, then the binder can join powder particles to form a three-dimensional object, but the binder does not provide sufficient visual contrast to enable reliable optical observation of quantity, geometric fidelity, and extent of cure

Engineering Contradiction:
Improveoptical observation capabilityVSAvoidbinder visibility
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The patent applies color changes by incorporating fluorescent materials into the binder composition. These fluorescent materials emit light at specific wavelengths when excited, creating high visual contrast between the binder and the powder bed. This enables reliable optical observation of binder quantity, geometric fidelity, and extent of cure during the additive manufacturing process, directly resolving the visibility issue while maintaining manufacturing capability

Inventive Principle:
Principle #32Color changes

2Measurement precision

If fluorescent material is added to the binder solution to enable optical monitoring, then visual feedback is improved, but the fluorescent material may be quenched by the powder bed material

Engineering Contradiction:
Improvebinder deposition monitoringVSAvoidfluorescence signal stability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent uses an encapsulating material as an intermediary between the fluorescent material and the powder bed. This encapsulation layer prevents direct contact and quenching interactions between the fluorescent molecules and the powder particles, while still allowing the fluorescent signal to pass through for optical detection. The intermediary protects the fluorescence signal stability without compromising the monitoring capability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs thin film encapsulation around the fluorescent material to isolate it from the quenching environment of the powder bed. This thin protective shell maintains the fluorescent properties by preventing direct interaction with powder particles, yet remains sufficiently transparent to allow optical monitoring systems to detect the fluorescence signal for binder deposition and cure extent measurement

Inventive Principle:
Principle #30Flexible shells and thin films

3Productivity

If too little binder is applied to the powder layer, then the print head may not be clogged, but the powder may not be sufficiently bound and part of the layer may be removed when the part is depowdered

Engineering Contradiction:
Improveprinting speedVSAvoidlayer binding strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent implements feedback by using optical monitoring systems to detect the actual amount of binder deposited on each layer. This real-time information allows the system to verify sufficient binder application before proceeding to the next layer, ensuring adequate layer binding strength. The feedback mechanism prevents both under-application (which would cause layer removal) and over-application (which would slow productivity through clogging), optimizing the printing process

Inventive Principle:
Principle #23Feedback

4Strength

If too much binder is applied, then the powder layer is well-bound, but the part may be moved or depowdered before sufficient strength is achieved, resulting in breakage or distortion

Engineering Contradiction:
Improvelayer binding strengthVSAvoidprinting speed
Core Design Contradiction:
StrengthVSProductivity

Solution Approach 1:

The patent uses feedback control through optical monitoring to precisely measure the amount of binder deposited. This enables the system to apply the optimal amount of binder - sufficient to achieve adequate layer binding strength without excess that would cause handling problems or require slower processing. The feedback mechanism ensures consistent binder application, maintaining productivity while preventing breakage and distortion

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate monitoring of binder quantity and cure extent, improving print quality by providing visual feedback during the additive manufacturing process.

Implementation Method 1

the binder solution fluoresces in response to exposure to electromagnetic radiation, thereby enabling the amount of binder solution present to be monitored using an optical system

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 2

the fluorescent material is encapsulated, either prior to addition into the binder solution or by one or more other components in the binder solution, to protect the fluorescent material from quenching by the material in the powder bed

Methodology Applied
Scientific EffectQuenching prevention:

Data Source

PatentUS11673323B2Fluorescent binders for use in monitoring additive manufacturing processes
Publication Date: 2023.06.13 GENERAL ELECTRIC CO
  • US11673323B2 patent drawing
  • US11673323B2 patent drawing
  • US11673323B2 patent drawing

AI summary

A method of manufacturing a green body part comprises depositing a layer of a powder on a working surface; and selectively depositing a binder solution comprising a thermoplastic binder, a fluorescent material, and a binder medium into the layer of powder in a pattern representative of a structure of a layer of the green body part. The thermoplastic binder comprises one or more polymer strands dissolved in a solvent medium having an average molecular weight from greater than or equal to 7,000 g/mol to less than or equal to 100,000 g/mol. Binder solutions comprising fluorescent material and green body parts adhered together using the same are also disclosed.