Organic Fluorescent Crystal Form for Durable Security Inks

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Solution Overview

Problem

Existing crystal forms of fluorescent compounds used in security printing lack thermal stability and chemical resistance, leading to issues with ink durability and longevity under harsh conditions.

Innovation Solution

Development of a new crystal form of a fluorescent compound characterized by specific X-ray diffraction peaks, which is thermally more stable and resistant to chemicals, providing improved thermal stability and chemical resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing crystal forms of fluorescent compounds are used in security printing, then the printing can be produced, but the ink lacks thermal stability and chemical resistance, leading to poor durability and longevity under harsh conditions

Engineering Contradiction:
Improveink durabilityVSAvoidthermal stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by discovering and utilizing a new crystal form (Form B) of the fluorescent compound with different molecular packing and intermolecular interactions. This crystal form exhibits enhanced thermal stability and chemical resistance compared to existing forms, directly improving ink durability under harsh conditions while maintaining the fluorescent properties needed for security printing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system by combining the new crystal form of the fluorescent compound with specific ink formulation components. This composite approach enhances both thermal stability and chemical resistance, resolving the contradiction between reliability and compositional stability in security printing inks

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing crystal forms of fluorescent compounds are used in security printing, then the printing can be produced, but the ink lacks chemical resistance, leading to poor durability under harsh conditions

Engineering Contradiction:
Improveink durabilityVSAvoidchemical resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent utilizes parameter changes by transitioning to a new crystal form (Form B) with altered molecular arrangement and stronger intermolecular forces. This structural parameter change confers superior chemical resistance to the ink, preventing degradation from chemical exposure while maintaining printability and fluorescent properties for security applications

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If existing crystal forms of fluorescent compounds are used in security printing, then the printing can be produced, but the ink lacks longevity under harsh conditions

Engineering Contradiction:
Improveink longevityVSAvoidthermal stability
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by discovering a new crystal form (Form B) with enhanced thermal stability characteristics. This structural parameter improvement directly extends the operational lifespan and longevity of the security printing ink, ensuring it maintains its properties under prolonged exposure to harsh thermal and chemical conditions

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The new crystal form exhibits enhanced thermal stability, chemical resistance, and longevity, making it suitable for security printing applications, particularly in banknotes, with improved process stability, reproducibility, and storage stability.

Implementation Method 1

characterized in an X-ray diffraction pattern by diffraction peaks corresponding to two theta scattering angles of 8.0; 12.3; 14.0 and 21.3

Methodology Applied
Scientific EffectX-ray diffraction: X-Ray

Implementation Method 2

The x-ray diffraction patterns are measured with Cu—Kalpha radiation

Methodology Applied
Scientific EffectDiffraction: Diffraction

Data Source

PatentUS12404273B2Crystal form of an organic fluorescent compound
Publication Date: 2025.09.02 BASF SE
  • US12404273B2 patent drawing
  • US12404273B2 patent drawing
  • US12404273B2 patent drawing

AI summary

The present invention relates to a new crystal form of the compound of formula and a process for its preparation. The compound may be used in compositions for inks, paints and plastics, especially in a wide variety of printing systems and is particularly well-suited for security applications.