Fluoride Spray Coating Ion Implantation for Corrosion Resistance

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Solution Overview

Problem

Conventional fluoride spray coatings are chemically unstable when exposed to halogen gases, leading to corrosion and color changes, and existing methods to improve stability, such as heat treatment, increase production costs and reduce efficiency.

Innovation Solution

A method of ion implanting F-containing gases, oxygen, or inert gases onto a white fluoride spray coating to form a black ion-implanted layer, which enhances corrosion resistance and plasma erosion resistance while allowing for visual identification and improved thermal radiation characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If heat treatment is applied to improve chemical stability of fluoride spray coating, then corrosion resistance is improved, but production cost increases and production efficiency decreases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidproduction efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies ion implantation during the spray coating process itself to pre-establish a stable fluoride layer, eliminating the need for subsequent heat treatment. This preliminary action achieves chemical stability at the time of coating formation, maintaining production efficiency while ensuring corrosion resistance.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces the thermal field (heat treatment) with an ion field (ion implantation) to achieve chemical stabilization. By using ion bombardment instead of thermal processing, the method achieves comparable or superior corrosion resistance without the time and energy costs associated with heat treatment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If heat treatment is applied to improve chemical stability of fluoride spray coating, then corrosion resistance is improved, but production cost increases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent combines the coating formation process with the stabilization process by integrating ion implantation into the spray coating operation. This merging of processes achieves both coating deposition and chemical stabilization in a single step, eliminating the separate heat treatment工序 and associated costs.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent replaces the thermal field (heat treatment) with an ion field (ion implantation) to achieve chemical stabilization. By using ion bombardment instead of thermal processing, the method achieves comparable or superior corrosion resistance without the time and energy costs associated with heat treatment.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Difficulty of detecting and measuring

If ion implantation is applied to blacken the coating surface, then visual identification capability is improved, but coating structure is modified

Engineering Contradiction:
Improvevisual identificationVSAvoidcoating composition
Core Design Contradiction:
Difficulty of detecting and measuringVSStability of the object's composition

Solution Approach 1:

The patent intentionally uses ion implantation to induce color change from white to black in the fluoride coating. This color transformation provides excellent visual identification capability for monitoring coating integrity and wear, while the ion implantation simultaneously enhances the chemical stability of the coating structure.

Inventive Principle:
Principle #32Color changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ion-implanted layer changes the appearance of the coating to black, maintaining corrosion and plasma erosion resistance, allowing for easier identification of wear and improving design, while maintaining the chemical and physical properties of the fluoride coating.

Implementation Method 1

a method of ion implanting F-containing gases, oxygen, or inert gases onto a white fluoride spray coating to form a black ion-implanted layer

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Data Source

PatentUS9238863B2Method for blackening white fluoride spray coating, and fluoride spray coating covered member having a blackened layer on its surface
Publication Date: 2016.01.19 TOCALO CO LTD
  • US9238863B2 patent drawing
  • US9238863B2 patent drawing
  • US9238863B2 patent drawing

AI summary

This invention is to provide a fluoride spray coating covered member having excellent resistance to halogen corrosion and resistance to plasma erosion and displaying identification symbols such as letters, numeric characters, graphic, pattern, firm name, serial number and so on. In the invention, one or more implanting gases selected from fluorine-containing gas, oxygen gas and inert gas are ion-implanted onto a white fluoride spray coating formed on a surface of a substrate, whereby at least a part of the surface of the white fluoride spray coating is changed into a black color to form a black ion-implanted layer.