Fluorinated Ether Surface Layer for Smartphone Abrasion and Sliding Resistance

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Solution Overview

Problem

Existing surface treatment agents using fluorinated ether compounds provide excellent abrasion resistance but are inferior in sliding resistance, leading to issues such as smartphones slipping and breaking when operated or placed on surfaces.

Innovation Solution

A composition comprising a fluorinated ether compound with a hydrolyzable silyl group at one terminal and another fluorinated ether compound with hydrolyzable silyl groups at both terminals, where the ratio of —CF3 to —CF2— groups at the terminals is within a specific range, is used to form a surface layer with enhanced abrasion and sliding resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a fluorinated ether compound with hydrolyzable silyl group is used for surface treatment, then abrasion resistance is improved, but sliding resistance deteriorates

Engineering Contradiction:
Improveabrasion resistanceVSAvoidsliding resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention changes the chemical composition parameters by specifying a particular ratio range of CF3 to CF2 groups (0.001 to 0.1) in the fluorinated ether compounds. This parameter optimization allows the surface layer to achieve both high abrasion resistance and improved sliding resistance, resolving the contradiction between these two properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite approach by combining multiple fluorinated ether compounds with different terminal group configurations (one terminal vs. both terminals). This composite material strategy enables the surface layer to exhibit both excellent abrasion resistance and sliding resistance simultaneously, overcoming the limitations of single-compound treatments.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If fluorinated ether compound provides excellent oil and fat stain removability, then flexibility is improved, but sliding resistance deteriorates

Engineering Contradiction:
Improvestain removabilityVSAvoidsliding resistance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

By optimizing the CF3/CF2 group ratio to within the specific range of 0.001 to 0.1, the invention adjusts the chemical parameters to achieve a balance where the surface maintains excellent stain removability while also providing adequate sliding resistance, preventing devices from slipping.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies different fluorinated ether compound structures at different locations within the surface layer composition. Compounds with silyl groups at one terminal provide stain removability, while compounds with silyl groups at both terminals contribute to sliding resistance, creating a functionally differentiated surface treatment.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed composition effectively forms a surface layer that balances abrasion resistance and sliding resistance, preventing smartphones and similar devices from slipping and breaking when handled or placed on surfaces.

Implementation Method 1

a compound represented by the formula (1) and a compound represented by the formula (2), wherein L1, L2 and L3 are each independently a hydrolyzable group or a hydroxy group

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

the ratio of the total number of moles of the groups represented by —CF3 present at the terminal of the fluorinated ether compounds, to the total number of moles of the groups represented by —CF2— present at a predetermined position in the fluorinated ether compounds

Methodology Applied
Scientific EffectCondensation:

Data Source

PatentUS12264257B2Composition containing a fluorinated ether compound
Publication Date: 2025.04.01 AGC INC
  • US12264257B2 patent drawing
  • US12264257B2 patent drawing
  • US12264257B2 patent drawing

AI summary

The composition containing a compound represented by the formula (1) and a compound represented by the formula (2),Rf1—(OX1)m1—O—Rf2—Y1—[Si(R1)n1L13-n1]g1  (1)[L23-n2(R2)n2Si]g2—Y2—Rf3—(OX2)m2—O—Rf4—Y3—[Si(R3)n3L33-n3]g3  (2),where Rf1 to Rf4, X1 to X2, Y1 to Y3, R1 to R3, L1 to L3, m1 to m2, n1 to n3, and g1 to g3 are as defined in the disclosure. An article, containing a substrate and a surface layer formed of the composition on the substrate.