Fluorinated Porous Materials for Chemical and Thermal Stability

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Solution Overview

Problem

Polyurethane foams are unstable in the presence of chemicals, oxidation, UV light, and thermal radiation, and they absorb organic solvents, leading to deformation and the production of toxic byproducts, limiting their applicability in harsh environments and biomedical applications.

Innovation Solution

Development of novel porous materials with improved acid and base stability, thermal stability, and biocompatibility, formed using a method involving coating porogens with a matrix material base, treating to fuse and cure, and removing the porogen scaffold to create a matrix with interconnected pores, suitable for various industrial and biomedical uses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If polyurethane foam is used for its versatility and structural geometry, then it can fulfill various industrial and household applications, but it becomes unstable in the presence of chemicals, oxidation, UV light, and thermal radiation

Engineering Contradiction:
Improveapplicability rangeVSAvoidstability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the foam material by replacing polyurethane with fluorinated polymers (such as PTFE and PVDF) that inherently possess resistance to chemicals, oxidation, UV light, and thermal radiation. This parameter change maintains the foam's structural geometry and versatility while fundamentally improving its stability and reliability in harsh environments.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategies by incorporating fluorinated polymer matrices with specific pore structures, creating a composite that combines the mechanical properties of foam with the chemical resistance of fluorinated polymers. This composite approach enables the material to simultaneously achieve versatility across applications and high stability in aggressive environments.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If polyurethane foam absorbs organic solvents to achieve formulation flexibility, then it can be produced in various densities and firmnesses, but it causes deformation of its structure due to swelling

Engineering Contradiction:
Improveformulation flexibilityVSAvoidstructural deformation
Core Design Contradiction:
Adaptability or versatilityVSShape

Solution Approach 1:

The patent changes the chemical resistance parameters by selecting fluorinated polymers that are inherently resistant to organic solvents. This parameter change allows the foam to maintain its formulation flexibility for producing various densities and firmnesses while preventing solvent-induced swelling and structural deformation.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If polyurethane foam is used in biomedical applications, then it can serve as scaffolds and medical device components, but it produces toxic byproducts during degradation

Engineering Contradiction:
Improvebiomedical applicabilityVSAvoidtoxic byproducts
Core Design Contradiction:
Adaptability or versatilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the biocompatibility parameters by replacing polyurethane with fluorinated polymers that do not produce toxic degradation byproducts. This parameter change enables the foam to maintain its versatility for biomedical applications such as scaffolds and medical device components while eliminating the harmful toxic byproducts generated during degradation.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS9522502B2Porous materials, methods of making and uses
Publication Date: 2016.12.20 ALLERGAN INC
  • US9522502B2 patent drawing
  • US9522502B2 patent drawing

AI summary

The present specification discloses porous materials, methods of forming such porous materials, materials and devices comprising such porous materials, and methods of making such materials and devices.