Fluorinated Propene Emulsions for Stable Personal Care Foams
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Solution Overview
Problem
Existing personal care formulations, such as skin lotions and shaving creams, face issues with rapid foaming, poor penetration of active ingredients, unattractive appearance, and skin irritation, particularly due to the use of volatile hydrocarbons and sensate ingredients, which also increase costs and may cause allergic reactions.
Innovation Solution
A stable oil-in-water emulsion composition comprising trans-1-chloro-3,3,3-trifluoropropene and trans-1-3,3,3-tetrafluoropropene, along with non-ionic and polymeric emulsifiers, that forms novel foam types like sherbet, ice cream, and crackling foams when dispensed, providing improved stability, penetration, and sensory experiences without the need for volatile hydrocarbons or sensates.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If volatile hydrocarbons are used to form foam in post-foam applications, then foaming capability is improved, but the formulation stability and skin penetration ability deteriorate
Solution Approach 1:
The patent changes the chemical parameters of the foaming agent from volatile hydrocarbons to fluorinated propene compounds (trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene), which have different volatility and reactivity characteristics. This parameter change allows the formulation to maintain stability while still achieving effective foaming, as the fluorinated compounds are less prone to degradation and provide more controlled foam formation.
2Speed
If volatile hydrocarbons are used to form foam quickly after application, then foaming speed is improved, but the ability to spread on skin and penetration into skin deteriorates
Solution Approach 1:
The patent employs preliminary action by formulating the product as a stable gel or emulsion that is ready for application but has delayed foaming. The fluorinated propene compounds remain stable in the formulation until applied, then gradually release to form foam. This allows the product to be spread on the skin in its stable gel form first, ensuring good distribution and penetration, before gradually forming foam for the intended effect.
3Object-affected harmful factors
If sensate ingredients are used to provide cooling sensation, then cooling effect is improved, but cost and risk of allergic reactions increase
Solution Approach 1:
The patent replaces expensive and potentially irritating sensate ingredients with a cheaper, safer alternative: the fluorinated propene compounds themselves provide a mild cooling effect through their evaporation and heat absorption, without the need for additional sensate additives. This eliminates the cost and allergy risk associated with traditional sensates while maintaining the desired cooling sensation.
4Illumination intensity
If microemulsion is used to improve transparency of emulsion formulation, then transparency is improved, but surfactant concentration and mixing energy requirements increase
Solution Approach 1:
The patent changes the physical parameters of the formulation by using fluorinated propene compounds that provide inherent clarity and light transmission. The unique optical properties of these fluorinated compounds allow the formulation to achieve transparency without requiring high surfactant concentrations or intensive mixing processes needed for traditional microemulsions.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution enhances the stability and penetration of active ingredients, provides immediate and long-lasting cooling sensations, and improves the aesthetic appeal of personal care products, while reducing skin irritation and costs.
Implementation Method 1
provide the user with the sensation of cooling as a result of application of the personal care product to the skin
Implementation Method 2
providing a personal care composition in a container under pressure in the form of a stable oil-in-water emulsion
Data Source
AI summary
A method of treating human skin, hair and/or mucous membranes using a personal care composition in the form of a stable oil-in-water emulsion comprising: (i) a continuous aqueous phase comprising water; (ii) a discontinuous oil phase comprising trans-1-chloro-3,3,3-trifluoropropene and/or trans-1-3,3,3-tetrafluoropropene and when present together are present in a trans1233zd:trans1234ze weight ratio of from about 1:18 to less than about 8:1; and (iii) an emulsifier, which may be present in the continuous and/or discontinuous phase, comprising (a) a non-ionic emulsifier having an HLB of from about 7 to about 19; and/or (b) a polymeric emulsifier.


