Fluorinated Propene Emulsions for Stable Personal Care Foams

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Solution Overview

Problem

Existing personal care formulations, such as skin lotions and shaving creams, face issues with rapid foaming, poor penetration of active ingredients, unattractive appearance, and skin irritation, particularly due to the use of volatile hydrocarbons and sensate ingredients, which also increase costs and may cause allergic reactions.

Innovation Solution

A stable oil-in-water emulsion composition comprising trans-1-chloro-3,3,3-trifluoropropene and trans-1-3,3,3-tetrafluoropropene, along with non-ionic and polymeric emulsifiers, that forms novel foam types like sherbet, ice cream, and crackling foams when dispensed, providing improved stability, penetration, and sensory experiences without the need for volatile hydrocarbons or sensates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If volatile hydrocarbons are used to form foam in post-foam applications, then foaming capability is improved, but the formulation stability and skin penetration ability deteriorate

Engineering Contradiction:
Improvefoaming capabilityVSAvoidformulation stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameters of the foaming agent from volatile hydrocarbons to fluorinated propene compounds (trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene), which have different volatility and reactivity characteristics. This parameter change allows the formulation to maintain stability while still achieving effective foaming, as the fluorinated compounds are less prone to degradation and provide more controlled foam formation.

Inventive Principle:
Principle #35Parameter changes

2Speed

If volatile hydrocarbons are used to form foam quickly after application, then foaming speed is improved, but the ability to spread on skin and penetration into skin deteriorates

Engineering Contradiction:
Improvefoaming speedVSAvoidspreadability on skin
Core Design Contradiction:
SpeedVSEase of operation

Solution Approach 1:

The patent employs preliminary action by formulating the product as a stable gel or emulsion that is ready for application but has delayed foaming. The fluorinated propene compounds remain stable in the formulation until applied, then gradually release to form foam. This allows the product to be spread on the skin in its stable gel form first, ensuring good distribution and penetration, before gradually forming foam for the intended effect.

Inventive Principle:
Principle #10Preliminary action

3Object-affected harmful factors

If sensate ingredients are used to provide cooling sensation, then cooling effect is improved, but cost and risk of allergic reactions increase

Engineering Contradiction:
Improvecooling sensationVSAvoidskin irritation and allergic reactions
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent replaces expensive and potentially irritating sensate ingredients with a cheaper, safer alternative: the fluorinated propene compounds themselves provide a mild cooling effect through their evaporation and heat absorption, without the need for additional sensate additives. This eliminates the cost and allergy risk associated with traditional sensates while maintaining the desired cooling sensation.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Illumination intensity

If microemulsion is used to improve transparency of emulsion formulation, then transparency is improved, but surfactant concentration and mixing energy requirements increase

Engineering Contradiction:
ImprovetransparencyVSAvoidsurfactant concentration and mixing energy
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent changes the physical parameters of the formulation by using fluorinated propene compounds that provide inherent clarity and light transmission. The unique optical properties of these fluorinated compounds allow the formulation to achieve transparency without requiring high surfactant concentrations or intensive mixing processes needed for traditional microemulsions.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances the stability and penetration of active ingredients, provides immediate and long-lasting cooling sensations, and improves the aesthetic appeal of personal care products, while reducing skin irritation and costs.

Implementation Method 1

provide the user with the sensation of cooling as a result of application of the personal care product to the skin

Methodology Applied
Scientific EffectEvaporative cooling: Evaporative Cooler

Implementation Method 2

providing a personal care composition in a container under pressure in the form of a stable oil-in-water emulsion

Methodology Applied
Scientific EffectEmulsion: Emulsion

Data Source

PatentUS20240342065A1Personal care compositions and methods comprising trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene
Publication Date: 2024.10.17 SOLSTICE ADVANCED MATERIALS US INC
  • US20240342065A1 patent drawing
  • US20240342065A1 patent drawing
  • US20240342065A1 patent drawing

AI summary

A method of treating human skin, hair and/or mucous membranes using a personal care composition in the form of a stable oil-in-water emulsion comprising: (i) a continuous aqueous phase comprising water; (ii) a discontinuous oil phase comprising trans-1-chloro-3,3,3-trifluoropropene and/or trans-1-3,3,3-tetrafluoropropene and when present together are present in a trans1233zd:trans1234ze weight ratio of from about 1:18 to less than about 8:1; and (iii) an emulsifier, which may be present in the continuous and/or discontinuous phase, comprising (a) a non-ionic emulsifier having an HLB of from about 7 to about 19; and/or (b) a polymeric emulsifier.