Fluorinated Silane Composition for Continuous Water- and Oil-Repellent Films

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Solution Overview

Problem

Existing compositions containing fluorine-containing silane compounds are unsuitable for forming continuous thin films with water-repellency and oil-repellency, particularly as sealing materials.

Innovation Solution

A curable composition comprising a fluorine-containing silane compound with two or more Si atoms bonded to hydroxyl or hydrolyzable groups, an organosilicon compound with —O—Rg3 groups, a catalyst, and a solvent, which allows for the formation of a continuous thin film with water-repellency and oil-repellency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a fluorine-containing silane compound is used in existing compositions, then water-repellency and oil-repellency are improved, but the ability to form a continuous thin film is deteriorated

Engineering Contradiction:
Improvewater-repellency and oil-repellencyVSAvoidcontinuous thin film formation
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention uses a composite system combining fluorine-containing silane compound (Formula 1) with organosilicon compound (Formula 2). The fluorine-containing silane provides water-repellency and oil-repellency, while the organosilicon compound with —O—Rg3 groups enables continuous thin film formation. This composite approach allows both functions to coexist without compromising either property.

Inventive Principle:
Principle #40Composite materials

2Reliability

If fluorine-containing silane compound with hydrolyzable groups is used, then sealing material properties are improved, but film continuity is deteriorated

Engineering Contradiction:
Improvesealing material suitabilityVSAvoidfilm continuity
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The organosilicon compound (Formula 2) acts as an intermediary that bridges the fluorine-containing silane compound and the substrate. The —O—Rg3 groups in the organosilicon compound facilitate film formation and continuity, while allowing the fluorine-containing silane to provide its sealing and repellency functions. This mediator enables both requirements to be satisfied simultaneously.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables the formation of a continuous thin film with enhanced water-repellency and oil-repellency, suitable for use as a sealing material.

Implementation Method 1

a fluorine-containing silane compound having two or more Si atoms each bonding to at least one group selected from the group consisting of a hydroxyl group and a hydrolyzable group

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

an organosilicon compound having at least two —O—Rg3 (s) each bonding to a Si atom

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS12454600B2Curable composition
Publication Date: 2025.10.28 DAIKIN INDUSTRIES LTD
  • US12454600B2 patent drawing
  • US12454600B2 patent drawing
  • US12454600B2 patent drawing

AI summary

A curable composition including a fluorine-containing silane compound having two or more Si atoms each bonding to at least one group selected from the group consisting of a hydroxyl group and a hydrolyzable group; an organosilicon compound having at least two —O—Rg3 (s) each bonding to a Si atom, wherein each Rg3, at each occurrence, is independently a hydrogen atom or a monovalent organic group; a catalyst; and a solvent.