Fluorine-Free Firefighting Foam Composition for Class B Fires

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Solution Overview

Problem

Conventional firefighting foams for Class B fires, which involve flammable liquids, often rely on fluorinated and perfluorinated surfactants, raising environmental concerns and necessitating the development of fluorine-free alternatives that can effectively suppress or extinguish these fires.

Innovation Solution

The development of aqueous firefighting foam compositions that are fluorine-free, comprising a sugar component, a surfactant component including anionic, zwitterionic, and nonionic surfactants, and a water-miscible organic solvent, which can be aerated to form a firefighting foam for suppressing hydrocarbon or volatile solvent fires.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluorinated and perfluorinated surfactants are used in firefighting foam, then fire suppression effectiveness is improved, but environmental harm increases

Engineering Contradiction:
Improvefire suppression effectivenessVSAvoidenvironmental harm
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent removes fluorinated and perfluorinated surfactants from the firefighting foam composition, extracting the harmful substances while retaining the essential fire suppression functionality through alternative non-fluorinated surfactant systems

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters by substituting fluorinated surfactants with non-fluorinated alternatives (such as hydrocarbon-based surfactants), thereby altering the chemical structure while maintaining the functional performance required for Class B fire suppression

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If fluorine-free surfactants are used to replace fluorinated surfactants, then environmental safety is improved, but fire suppression effectiveness may deteriorate

Engineering Contradiction:
Improveenvironmental safetyVSAvoidfire suppression effectiveness
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent employs composite surfactant systems combining multiple non-fluorinated surfactant types (anionic, cationic, nonionic, and amphoteric surfactants) to achieve synergistic effects that maintain fire suppression effectiveness while eliminating fluorinated compounds

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent designs a multi-functional surfactant system where non-fluorinated surfactants perform multiple roles: reducing surface tension for foam formation, providing fire suppression, and ensuring environmental safety, thereby replacing the specialized fluorinated surfactants with a versatile alternative system

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compositions effectively form firefighting foams that can suppress vapors and fight Class B fires without the environmental drawbacks of fluorinated surfactants, ensuring a safer and more sustainable firefighting solution.

Implementation Method 1

The diluted foam precursor composition can be aerated to form a firefighting foam

Methodology Applied
Scientific EffectAeration: Aeration

Implementation Method 2

a surfactant component comprising an anionic surfactant, a zwitterionic surfactant, and/or a nonionic surfactant

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Data Source

PatentUS20250144461A1Fire-fighting foam composition
Publication Date: 2025.05.08 TYCO FIRE PRODUCTS LP

AI summary

An aqueous fluorine-free, fire-fighting composition including a sugar component, an anionic surfactant, a zwitterionic surfactant, water-miscible organic solvent, and a nonionic surfactant, is provided.