Fluorine-Shelled Quantum Dots for Stable High-Yield Emission

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current light emitting elements using quantum dots face challenges in achieving high luminous efficiency and color reproducibility, with existing methods struggling to enhance these aspects effectively.

Innovation Solution

A quantum dot is developed with a core composed of copper, indium, and gallium, surrounded by a shell including fluorine and a Group II-VI compound, such as ZnS, formed through a method involving hydrofluoric acid treatment, which improves chemical stability and luminous efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a quantum dot with core-shell structure is developed using hydrofluoric acid treatment, then chemical stability and quantum yield are improved, but manufacturing complexity increases

Engineering Contradiction:
Improvechemical stabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by performing hydrofluoric acid treatment on the core surface before shell formation. This pre-treatment removes surface defects and prepares the core for subsequent shell deposition, ensuring high chemical stability and quantum yield. The core is pre-modified with fluorine atoms that facilitate controlled shell growth and prevent aggregation during the manufacturing process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses hydrofluoric acid as an intermediary substance that mediates between the core and shell formation processes. The acid treatment creates a controlled surface environment that enables uniform shell deposition while maintaining core integrity. This intermediary treatment step acts as a bridge that ensures optimal interface between core and shell, resolving the complexity by providing a standardized preparation protocol.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If quantum yield and color reproducibility are enhanced through shell formation, then luminous efficiency improves, but production time increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidproduction time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent implements continuous useful action by performing shell formation in a single continuous reaction process rather than multiple discrete steps. The sulfur precursor and metal precursors are introduced simultaneously or in continuous sequence, allowing uninterrupted shell growth on the pre-treated core surface. This continuous process maintains high luminous efficiency while minimizing production time by eliminating intermediate processing steps.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent applies parameter changes by optimizing reaction conditions such as temperature, precursor concentrations, and reaction time to achieve rapid shell formation. By carefully controlling these parameters, the shell forms uniformly and quickly on the core surface, enhancing quantum yield and color reproducibility without significantly extending production time. The reaction temperature and precursor ratios are tuned to maximize deposition rate while maintaining quality.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The quantum dot exhibits high quantum yield and retention rate, leading to enhanced luminous efficiency and color reproducibility, with a quantum yield retention rate of at least 90% and a full width at half maximum (FWHM) of emission wavelength spectrum less than 60 nm, improving chemical stability and optical performance.

Implementation Method 1

reacting the surface of the core with the hydrofluoric acid, wherein halogen ions bonded to the surface of the core may be removed through the reacting of the surface of the core with the hydrofluoric acid

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

reacting the surface of the core with the Group II element precursor and the Group VI element precursor

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

a quantum dot exhibiting a high quantum yield and excellent chemical stability

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS20250101298A1Quantum dot, method for preparing the quantum dot, and light emitting element comprising the quantum dot
Publication Date: 2025.03.27 SAMSUNG DISPLAY CO LTD
  • US20250101298A1 patent drawing
  • US20250101298A1 patent drawing
  • US20250101298A1 patent drawing

AI summary

Embodiments provide a quantum dot, a method for preparing a quantum dot, and a light emitting element including the quantum dot. The method for preparing a quantum dot includes forming a core including a copper atom, an indium atom, a gallium atom, and a sulfur atom, and forming a shell surrounding the core by reacting the surface of the core with hydrofluoric acid, a Group II element precursor, and a Group VI element precursor.