Fluoro-Substituted OLED Compound for Solution Processed Layers

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Solution Overview

Problem

Conventional deposition processes for manufacturing organic light emitting devices result in significant material loss and difficulties in producing large-area devices, necessitating the development of materials suitable for solution processes.

Innovation Solution

A novel compound represented by Chemical Formula 1 is used in a coating composition for forming organic material layers, enabling the production of organic light emitting devices with low driving voltage, high luminous efficiency, and long lifespan through a solution process, where the compound contains four or more fluoro groups for enhanced hole-mobility and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a deposition process is used to manufacture organic light emitting devices, then device performance can be achieved, but significant material loss occurs and large-area device production becomes difficult

Engineering Contradiction:
Improvedevice performanceVSAvoidmaterial loss
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent replaces the vacuum deposition process (mechanical/physical method) with a solution processing method (chemical method). The compound is dissolved in a solvent to form a coating solution, which is then applied to the substrate and dried to form the organic material layer. This substitution eliminates the material loss inherent in deposition processes while enabling large-area production through techniques like spin coating, dip coating, or inkjet printing.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical state of the organic compound from a solid material requiring vacuum deposition to a soluble compound that can be processed in liquid solution. By introducing specific molecular structures (compounds of formula 1 with appropriate functional groups), the compound gains solubility in common organic solvents, enabling solution processing and eliminating the need for vacuum deposition equipment.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a deposition process is used to manufacture organic light emitting devices, then device performance can be achieved, but production of large-area devices becomes difficult

Engineering Contradiction:
Improvedevice performanceVSAvoiddevice area
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The patent replaces vacuum deposition with solution processing methods that are inherently more suitable for large-area production. Techniques such as spin coating, dip coating, spray coating, and inkjet printing can easily cover large substrates uniformly. The solution can be applied to substrates of any size, and the coating process can be scaled up for mass production of large-area OLEDs without the material waste and equipment limitations of vacuum deposition.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If conventional materials are used in solution processes, then large-area production is enabled, but material solubility and stability in solution are insufficient

Engineering Contradiction:
Improveproduction capabilityVSAvoidmaterial solubility and stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent modifies the molecular structure of the organic compound to introduce specific functional groups and structural features that enhance solubility in common organic solvents. The compound of formula 1 includes electron-donating or electron-withdrawing groups, bulky substituents, or flexible chains that improve solvation. Additionally, the molecular weight and structural rigidity are optimized to ensure the compound remains stable in solution without premature precipitation or degradation, enabling reliable solution processing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound facilitates the formation of devices with low voltage, high efficiency, and extended lifespan, allowing for large-area device production without performance deterioration due to its solubility and stability in solution processes.

Implementation Method 1

the compound contains four or more fluoro groups for enhanced hole-mobility and stability

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

If a current is applied between the two electrodes when an organic material layer is positioned between an anode and a cathode, electrons and holes are respectively injected into the organic material layer from the cathode and the anode. The electrons and holes injected into the organic material layer recombine to form excitons, and light is emitted as these excitons are falling back to the ground state.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP4180416B1Novel compound, coating composition comprising same, organic light-emitting device using same, and manufacturing method therefor
Publication Date: 2024.11.27 LG CHEM LTD
  • EP4180416B1 patent drawing
  • EP4180416B1 patent drawing
  • EP4180416B1 patent drawing

AI summary

The present disclosure relates to a compound represented by Chemical Formula 1, a coating composition comprising the compound represented by Chemical Formula 1 above, an organic light emitting device using the coating composition, and a method for manufacturing the organic light emitting device.