Fluorocarbon Etching Uniformity via Cyclic Plasma

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Solution Overview

Problem

Existing methods for etching semiconductor devices struggle to achieve uniformity and selectivity in forming wide and narrow features, as they are often dependent on feature geometry and aspect ratio, leading to variations in etching results.

Innovation Solution

A cyclical process involving ion bombardment to create activated sites, exposure to fluorocarbon molecules for self-limiting binding, and subsequent ion bombardment to initiate an etch reaction, ensuring uniform etching independent of feature geometry and aspect ratio.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional etching methods are used, then etching can be performed on semiconductor layers, but uniformity and selectivity deteriorate due to dependence on feature geometry and aspect ratio

Engineering Contradiction:
Improveetching uniformityVSAvoiddependence on feature geometry
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The patent applies periodic action by implementing a cyclical etching process that alternates between plasma activation phases and fluorocarbon deposition phases. This periodic cycling allows controlled creation of activated sites followed by selective fluorocarbon binding, achieving uniform etching independent of feature geometry or aspect ratio variations

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent utilizes parameter changes by transitioning between different plasma states (activation vs. deposition modes) and controlling fluorocarbon molecule exposure timing. By dynamically adjusting plasma power, pressure, and gas flow parameters during cyclic operation, the process achieves aspect ratio independent etching with high uniformity across different feature dimensions

Inventive Principle:
Principle #35Parameter changes

2Productivity

If plasma is continuously provided for etching, then etching speed increases, but selectivity and self-limiting binding capability are lost

Engineering Contradiction:
Improveetching speedVSAvoidselective binding capability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent implements periodic action by extinguishing plasma between activation and deposition steps. This allows fluorocarbon molecules to selectively bind to activated sites without continuous plasma interference, maintaining self-limiting binding behavior while achieving efficient etching through repeated cycling

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent applies preliminary action by creating activated sites through ion bombardment before introducing fluorocarbon molecules. This pre-activation ensures that fluorocarbon binding occurs only at specific activated locations, providing selective and self-limiting deposition that maintains reliability while enabling subsequent rapid etching

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in highly uniform and selective etching with minimal variations in within-wafer and wafer-to-wafer repeatability, achieving consistent results across different feature widths and aspect ratios.

Implementation Method 1

providing by creating a plasma an ion bombardment of the etch layer to create activated sites of surface radicals

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

providing by creating a plasma an ion bombardment of the etch layer to create activated sites of surface radicals

Methodology Applied
Scientific EffectIon bombardment: Ion Beam

Implementation Method 3

exposing the etch layer to a plurality of fluorocarbon containing molecules, which causes the fluorocarbon containing molecules to selectively bind to the activated sites, wherein the selective binding is self limiting

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

providing an ion bombardment of the etch layer to initiate an etch reaction between the fluorocarbon containing molecules and the etch layer

Methodology Applied
Scientific EffectIon bombardment: Ion Beam

Implementation Method 5

providing an ion bombardment of the etch layer to initiate an etch reaction between the fluorocarbon containing molecules and the etch layer, wherein the ion bombardment of the etch layer to initiate an etch reaction causes the formation of volatile etch products

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS9257300B2Fluorocarbon based aspect-ratio independent etching
Publication Date: 2016.02.09 LAM RES CORP
  • US9257300B2 patent drawing
  • US9257300B2 patent drawing
  • US9257300B2 patent drawing

AI summary

A method for etching features into an etch layer disposed below a patterned mask is provided. At least three cycles are provided, where each cycle comprises providing an ion bombardment, by creating a plasma, of the etch layer to create activated sites of surface radicals in parts of the etch layer exposed by the patterned mask, extinguishing the plasma, exposing the etch layer to a plurality of fluorocarbon containing molecules, which causes the fluorocarbon containing molecules to selectively bind to the activated sites, wherein the selective binding is self limiting, and providing an ion bombardment of the etch layer to initiate an etch reaction between the fluorocarbon containing molecule and the etch layer, wherein the ion bombardment of the etch layer to initiate an etch reaction causes the formation of volatile etch products formed from the etch layer and the fluorocarbon containing molecule.