Fluoroelastomer Coated Elastomeric Tooling for Composite Manufacturing

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Solution Overview

Problem

Conventional elastomeric tooling materials, such as silicone and EPDM, interact negatively with epoxy-based resin systems, leading to contamination, degradation, and limitations in mechanical properties, while fluoroelastomers offer chemical inertness but are expensive and difficult to repair, and fluoropolymer encapsulants cause delamination and wrinkles during composite manufacturing.

Innovation Solution

A tooling structure comprising a thin fluoroelastomer outer layer bonded with a base elastomer, such as silicone or EPDM, using an interface layer like VMQ silicone, allowing for cost-effective, flexible, and chemically inert tooling that avoids autoclave processing and reduces delamination and wrinkles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional elastomeric tooling materials (silicone, EPDM) are used, then cost and ease of manufacture are improved, but chemical compatibility with epoxy resin systems deteriorates leading to contamination and degradation

Engineering Contradiction:
Improveease of manufactureVSAvoidchemical compatibility
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The tooling is divided into multiple layers with different materials: an inner layer of conventional elastomer (silicone or EPDM) for structural integrity and ease of manufacture, and an outer layer of fluoroelastomer for chemical compatibility with epoxy resin systems. This segmentation allows each layer to perform its optimal function without compromise

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite structure combining conventional elastomeric materials with fluoroelastomer materials. The composite provides both the manufacturing advantages of conventional materials and the chemical resistance of fluoroelastomers, resolving the contradiction between ease of manufacture and chemical compatibility

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If fluoroelastomer is used for the entire tooling, then chemical inertness with epoxy resin systems is improved, but cost and difficulty of repair worsen

Engineering Contradiction:
Improvechemical inertnessVSAvoidcost and repair difficulty
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

Instead of making the entire tooling from expensive fluoroelastomer, only the outer surface layer that contacts the epoxy resin is made of fluoroelastomer. The inner structural layers use more cost-effective conventional elastomers. This local application of fluoroelastomer provides chemical inertness where needed while reducing overall cost and improving repairability

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The tooling is segmented into an outer fluoroelastomer layer for chemical resistance and inner conventional elastomer layers for structural support. This segmentation allows the expensive fluoroelastomer to be used only where chemically necessary, reducing overall cost while maintaining chemical inertness at the resin interface

Inventive Principle:
Principle #1Segmentation

3Object-affected harmful factors

If fluoropolymer encapsulants are used, then chemical protection is improved, but structural integrity deteriorates due to delamination and wrinkles

Engineering Contradiction:
Improvechemical protectionVSAvoidstructural integrity
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The invention uses a composite material system where fluoroelastomer and conventional elastomer are chemically bonded through co-curing processes. This creates a unified composite structure that maintains structural integrity while providing chemical protection, avoiding the delamination and wrinkle problems associated with physical encapsulation

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The fluoroelastomer layer acts as an intermediary between the epoxy resin system and the inner conventional elastomer layers. It provides chemical protection while being chemically bonded to both the resin and the inner layer, preventing delamination and maintaining structural integrity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution provides a cost-effective, chemically inert, and mechanically robust elastomeric tooling that minimizes interactions with epoxy resin systems, reduces production costs, and prevents delamination and wrinkles, enabling efficient composite manufacturing without the need for autoclave processing.

Implementation Method 1

fluoroelastomers offer chemical inertness

Methodology Applied
Scientific EffectChemical inertness:

Implementation Method 2

an elastomeric interface layer positioned between the elastomeric outer layer and the elastomeric inner layer. the elastomeric interface layer facilitates adhesion between the elastomeric outer layer and the elastomeric inner layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

the elastomeric tooling is a bladder, the elastomeric inner layer substantially defines an inner cavity, and the elastomeric tooling can be expanded by applying a positive pressure to the inner cavity

Methodology Applied
Scientific EffectPressure expansion: Pressure Increase

Data Source

PatentUS11642816B2Fluoroelastomer covered elastomeric tooling for composite manufacturing
Publication Date: 2023.05.09 RUBBERCRAFT CORP OF CALIFORNIA LTD
  • US11642816B2 patent drawing
  • US11642816B2 patent drawing
  • US11642816B2 patent drawing

AI summary

A multi-layer elastomeric tooling for the manufacturing of composite structures is disclosed. The tooling comprises an elastomeric base material with an outer layer of fluoroelastomer. The base material can, in certain embodiments, be selected for its mechanical or thermal performance or low cost without the limitation of being a contact material. The outer material can, in various embodiments, have inferior mechanical properties, or durometers different than the base material or can be a contact or barrier material.