Fluoropolymer Coating Composition for Mold Release Durability

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Solution Overview

Problem

Existing fluoropolymer coatings used for mold release experience a decrease in releasability upon repeated use and require frequent re-application, which is not satisfactory in terms of durability and productivity.

Innovation Solution

A fluoropolymer coating composition containing a fluoropolymer and a liquid oil with a decomposition temperature higher than the melting point of the fluoropolymer, where the oil is dispersed in the coating composition and heat-treated to form a coating film with enhanced non-adhesiveness and wear resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluoropolymer coating is applied to mold surface for release, then releasability is improved, but durability deteriorates due to decrease in releasability upon repeated use

Engineering Contradiction:
ImprovereleasabilityVSAvoiddurability
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The coating composition incorporates a plasticizer that migrates to the coating surface during molding cycles, dynamically replenishing the release properties. This self-adjusting mechanism maintains releasability over time rather than degrading, resolving the contradiction between initial releasability and long-term durability

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The invention changes the chemical composition parameters by selecting specific plasticizers with appropriate molecular weights and chemical structures that remain stable at molding temperatures. This parameter optimization ensures the plasticizer continues to provide release properties without degrading, extending the coating's functional life

Inventive Principle:
Principle #35Parameter changes

2Reliability

If fluoropolymer coating is used for mold release, then non-adhesiveness is improved, but productivity deteriorates due to frequent re-application requirements

Engineering Contradiction:
Improvenon-adhesivenessVSAvoidproductivity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The coating system performs self-service by automatically replenishing its release properties through plasticizer migration during normal molding operations. This eliminates the need for external re-application interventions, maintaining non-adhesiveness while improving productivity through continuous operation

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The plasticizer ensures continuous release functionality throughout the coating's service life by migrating to replenish surface properties. This continuous action prevents interruptions for re-application, thereby maintaining both non-adhesiveness and productivity

Inventive Principle:
Principle #20Continuity of useful action

3Reliability

If fluoro oil is added to fluoropolymer coating composition, then releasability is improved, but cost increases due to expensive fluoro oil

Engineering Contradiction:
ImprovereleasabilityVSAvoidcost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention replaces expensive fluoro oil with a more economical plasticizer that achieves the same release function. Although the plasticizer migrates and depletes over time, its lower cost compensates for this, providing a cost-effective solution that maintains releasability without the high material cost of fluoro oil

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention changes the material selection parameters by choosing plasticizers with appropriate molecular weights, chemical structures, and prices that optimize both performance and cost. This parameter optimization achieves releasability comparable to fluoro oil formulations at significantly lower material cost

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating film exhibits excellent releasability and wear resistance over a long period, reducing the need for frequent re-application and improving mold productivity.

Implementation Method 1

the oil migrates to the surface of the coating film

Methodology Applied
Scientific EffectMigration: Diffusion

Implementation Method 2

heat-treated to form a coating film

Methodology Applied
Scientific EffectHeat treatment: Heating

Implementation Method 3

melting point of the fluoropolymer

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentUS11926754B2Fluoropolymer coating composition
Publication Date: 2024.03.12 THE CHEMOURS CO FC LLC

AI summary

Provided is a coating film having excellent durability and wear resistance, and utility as mold surface release coating. The coating film has excellent releasability (non-adhesiveness) over a long period of time. Further provided is a coating composition capable of forming such a coating film, the coating composition containing a fluoropolymer and an oil that is a liquid at 25° C., wherein the decomposition temperature of the oil is higher than the melting point of the fluoropolymer.