Fluororesin-Siloxane Fixing Member Surface for Wax Offset Control

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Solution Overview

Problem

Existing fixing members in electrophotographic image forming apparatuses experience gloss unevenness, known as wax offset, when using fluororesin surfaces due to insufficient toner releasability, particularly on high-quality media like transparent films and high-gloss papers.

Innovation Solution

A fixing member with a surface layer having a sliding angle of 25 degrees or less at 150°C with respect to Fischer-Tropsch wax having a melting point of 90°C and a penetration of 3 (1/10 mm) is employed, enhancing toner releasability and reducing wax offset.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluororesin surface is used for fixing member, then heat resistance and chemical stability are improved, but gloss unevenness (wax offset) occurs due to insufficient toner releasability

Engineering Contradiction:
Improveheat resistance and chemical stabilityVSAvoidgloss unevenness (wax offset)
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The surface layer is formed as a composite material comprising a fluororesin base resin and a siloxane compound. This composite structure combines the heat resistance and chemical stability of fluororesin with the low surface energy and excellent releasability of siloxane, thereby suppressing gloss unevenness while maintaining the beneficial properties of fluororesin.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the chemical composition parameters of the surface layer by incorporating a siloxane compound with specific structural characteristics ( Formula (1) where R represents a specific organic group). This parameter change modifies the surface energy characteristics to achieve a sliding angle of 25° or less, improving toner releasability without sacrificing the thermal and chemical stability provided by the fluororesin matrix.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If mold release agent is applied to improve toner releasability, then fixing performance is improved, but gloss unevenness occurs on high-quality media surfaces

Engineering Contradiction:
Improvetoner releasabilityVSAvoidimage quality uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The siloxane compound acts as an intermediary substance within the surface layer that provides the necessary releasability function. Instead of applying a separate mold release agent that can transfer to media, the siloxane is integrated into the surface layer structure itself, mediating between the toner and the fluororesin substrate to enable smooth release without causing gloss unevenness on high-quality media.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention replaces the mechanical application of mold release agents with an intrinsic surface property approach. The siloxane-containing surface layer inherently provides low friction and excellent releasability through its molecular structure, eliminating the need for separate release agents that could transfer to media and cause gloss unevenness.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively suppresses gloss unevenness, ensuring high-quality image printing on smooth surfaces by minimizing the presence of mold release agents on the fixing member surface.

Implementation Method 1

a surface layer having a sliding angle of 25 degrees or less at 150° C. with respect to a Fischer-Tropsch wax

Methodology Applied
Scientific EffectFriction: Friction

Data Source

PatentUS20250271795A1Fixing member, fixing device, and image forming apparatus
Publication Date: 2025.08.28 FUJIFILM BUSINESS INNOVATION CORP
  • US20250271795A1 patent drawing
  • US20250271795A1 patent drawing
  • US20250271795A1 patent drawing

AI summary

A fixing member includes a surface layer having a sliding angle of 25 degrees or less at 150° C. with respect to a Fischer-Tropsch wax having a melting point of 90° C. and a penetration of 3 ( 1/10 mm).