Fluted Anode Capacitor Conformal Cathode ESR Reduction

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Solution Overview

Problem

The existing methods for forming cathode layers in solid electrolytic capacitors fail to conform to the shape of fluted anodes, resulting in inconsistent thickness and limited advantages from the use of fluted anodes, which restricts the reduction of Equivalent Series Resistance (ESR) and volumetric efficiency.

Innovation Solution

A method involving electrochemical polymerization using conductive nodes to form a conformal cathode on a fluted anode, with a plated metal layer and carbon adhesion layer, allowing for a consistent thickness and improved adhesion to the anode, thereby reducing ESR and enhancing volumetric efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional cathode layer formation methods are used, then the cathode layers are easier to manufacture, but the thickness is inconsistent and the fluted anode advantages are not fully realized

Engineering Contradiction:
Improvecathode layer thickness consistencyVSAvoidcathode layer formation complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent replaces conventional mechanical or chemical dip-coating methods with electrochemical polymerization. By applying electrical current, the conductive polymer forms conformally on the fluted anode surface through electrochemical reactions, ensuring uniform thickness even in narrow flutes where conventional methods fail.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces conductive nodes as intermediaries to facilitate the electrochemical polymerization process. These nodes enable electrical contact with the cathode layers formed in narrow flutes, allowing the polymerization reaction to proceed uniformly across the entire anode surface including deep within the flutes.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Volume of moving object

If fluted anodes with narrow flutes are used, then volumetric efficiency and capacitance recovery are improved, but the cathode layers cannot conform to the flute dimensions

Engineering Contradiction:
Improvevolumetric efficiencyVSAvoidcathode layer conformality
Core Design Contradiction:
Volume of moving objectVSManufacturing precision

Solution Approach 1:

The patent uses electrochemical polymerization instead of mechanical coating methods. This electrochemical approach allows the cathode layers to grow conformally on the complex three-dimensional fluted surface, penetrating into narrow flutes and adhering to the contours that conventional mechanical methods cannot achieve.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the formation method parameters from passive coating to active electrochemical growth. By controlling electrical current density, voltage, and polymerization time, the cathode layers can be precisely formed to conform to the fluted geometry, achieving both narrow flute dimensions and uniform layer thickness.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If cathode layers pool in the flutes, then the flutes are filled, but the thickness becomes inconsistent and ESR reduction is limited

Engineering Contradiction:
ImproveESR reductionVSAvoidcathode layer thickness uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent replaces gravity-dependent pouring or dipping methods with electrochemical polymerization driven by electrical current. This ensures uniform current distribution across the fluted surface, producing consistent cathode layer thickness throughout the flutes rather than pooling at the bottom where gravity would cause accumulation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent creates equipotential conditions across the fluted anode surface during polymerization. By ensuring uniform electrical potential distribution, the electrochemical reaction proceeds at consistent rates across all surfaces including within flutes, eliminating thickness variations caused by gravitational pooling.

Inventive Principle:
Principle #12Equipotentiality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The conformal cathode approach achieves a significant reduction in ESR and improved volumetric efficiency, enabling the use of narrower flutes and increased flute density, leading to reduced capacitor costs and increased reliability.

Implementation Method 1

applying voltage to the anode wire; electrochemically depositing conductive polymer on the first conductive layer to form conformal cathode

Methodology Applied
Scientific EffectElectrochemical polymerization: Electrodeposition

Implementation Method 2

a plated metal layer is on the carbon layer

Methodology Applied
Scientific EffectMetal plating: Electroplating

Data Source

PatentUS9959979B2Low ESR capacitor
Publication Date: 2018.05.01 KEMET ELECTRONICS CORP
  • US9959979B2 patent drawing
  • US9959979B2 patent drawing
  • US9959979B2 patent drawing

AI summary

An improved capacitor is provided wherein the improved capacitor has improved ESR. The capacitor has a fluted anode and an anode wire extending from the fluted anode. A dielectric is on the fluted anode. A conformal cathode is on the dielectric and a plated metal layer is on the carbon layer.