Flux-Cored Wire Composition for Low-Spatter CO2 Welding

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Solution Overview

Problem

Existing flux-cored wires for gas shielded arc welding face challenges in achieving high strength, high toughness, and low spatter generation, particularly when using 100% CO2 as a shielding gas, and often require preheating to prevent cold-cracking, which increases operational costs and complexity.

Innovation Solution

A flux-cored wire with a specific chemical composition, including 0.11% or more of certain fluorides, 4.30% to 7.50% TiO2, and controlled amounts of oxides and carbonates, which reduces diffusible hydrogen to 1.0 ml/100 g and spatter generation to 3.5 g/min or less, enabling all-position welding without preheating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If rutile-based flux-cored wire with large amount of TiO2 is used, then welding workability and suppression of molten metal dripping are improved, but the basicity of slag becomes low, causing increased oxygen content in weld metal and reduced toughness

Engineering Contradiction:
Improvewelding workabilityVSAvoidweld metal toughness
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent changes the chemical composition parameters of the flux by strictly controlling the TiO2 content (4.0-7.0 wt%) and introducing specific oxide combinations (CaO: 0.1-0.5 wt%, MgO: 0.1-0.5 wt%, SiO2: 0.1-0.5 wt%, Al2O3: 0.1-0.5 wt%) to adjust slag basicity while maintaining welding workability. This parameter optimization resolves the contradiction between ease of operation and weld metal toughness.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If 100% CO2 gas is used as shielding gas, then welding efficiency is improved, but the amount of spatter generated increases significantly

Engineering Contradiction:
Improvewelding efficiencyVSAvoidspatter generation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the flux composition parameters by controlling TiO2 (4.0-7.0 wt%) and adding specific oxides (CaO, MgO, SiO2, Al2O3 each 0.1-0.5 wt%) to modify slag properties. This optimization reduces spatter generation during 100% CO2 welding while maintaining high welding efficiency, resolving the contradiction between productivity and spatter control.

Inventive Principle:
Principle #35Parameter changes

3Strength

If conventional flux-cored wire is used to achieve high strength weld metal, then tensile strength is improved, but cold-cracking resistance deteriorates, requiring preheating operations

Engineering Contradiction:
Improveweld metal tensile strengthVSAvoidcold-cracking resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent creates a composite flux system combining multiple oxides (TiO2, CaO, MgO, SiO2, Al2O3) with specific proportions. This composite composition achieves both high tensile strength (≥490 MPa) and excellent cold-cracking resistance, eliminating the need for preheating operations while maintaining high strength, thus resolving the contradiction between strength and reliability.

Inventive Principle:
Principle #40Composite materials

4Reliability

If preheating operation is performed to prevent cold-cracking, then cold-cracking resistance is improved, but manufacturing complexity and operational costs increase

Engineering Contradiction:
Improvecold-cracking resistanceVSAvoidwelding process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The flux-cored wire is designed to be self-protecting through its optimized composition (TiO2: 4.0-7.0 wt%, CaO: 0.1-0.5 wt%, MgO: 0.1-0.5 wt%, SiO2: 0.1-0.5 wt%, Al2O3: 0.1-0.5 wt%). The flux automatically provides cold-cracking resistance without requiring external preheating operations, achieving self-service functionality that simplifies the welding process and reduces operational complexity.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves high strength, toughness, and reduced spatter in welds, eliminating the need for preheating and improving welding workability across various positions, especially with 100% CO2 shielding gas.

Implementation Method 1

a flux-cored wire for gas shielded arc welding, by which a weld metal having high strength and high toughness is obtained, all-position welding can be performed, the amount of spatter generated during a welding operation can be reduced

Methodology Applied
Scientific EffectHydrogen control through flux composition:

Implementation Method 2

the amount of spatter generated during a welding operation can be reduced even when a shielding gas is a gas that easily generates spatter, such as 100% CO2 gas

Methodology Applied
Scientific EffectSpatter reduction through flux composition:

Implementation Method 3

gas shielded arc welding

Methodology Applied
Scientific EffectArc welding: Electric Arc

Implementation Method 4

a weld metal having high strength and high toughness is obtained

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS11400539B2Flux-cored wire, manufacturing method of welded joint, and welded joint
Publication Date: 2022.08.02 NIPPON STEEL CORPORATION
  • US11400539B2 patent drawing
  • US11400539B2 patent drawing
  • US11400539B2 patent drawing

AI summary

A flux-cored wire according to an aspect of the present invention includes: a steel sheath; and a flux filling the inside of the steel sheath, in which the flux contains 0.11% or more in total of a fluoride in terms of F-equivalent value, 4.30% to 7.50% of a Ti oxide in terms of TiO2 equivalent, 0.30% to 2.40% in total of an oxide in terms of mass %, and 0% to 0.60% in total of a carbonate in terms of mass %, the amount of a Ca oxide in terms of CaO is less than 0.20% in terms of mass %, the amount of CaF2 is less than 0.50%, a chemical composition of the flux-cored wire is within a predetermined range, a Z value is 2.00% or less, a V value is 5.0 to 27.0, and Ceq is 0.30% to 1.00% or less.