Flux-Cored Aluminum Welding Wire for 7XXX Hot Crack Reduction

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Solution Overview

Problem

7XXX aluminum alloy welding faces challenges such as severe hot cracking tendency, coarse grains, and mechanical performance degradation due to high cost of micro- and nano-particle reinforcement and poor wettability, limiting the application of existing welding materials.

Innovation Solution

A flux-cored welding wire filled with a mixed salt and rare earth elements, where the mixed salt reacts in-situ to produce nanoparticles, enhancing bonding and refining grains, and reducing production costs, while the rare earth elements improve grain refinement and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If micro- and nano-particle reinforcement is used to improve weld strength and grain refinement, then weld mechanical performance is improved, but production cost increases significantly

Engineering Contradiction:
Improveweld strengthVSAvoidproduction cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The flux-cored welding wire contains mixed salts (such as CaF2, AlF3, SiO2) that react in-situ during welding to generate fine particles automatically. This self-generating mechanism eliminates the need for external micro- and nano-particle reinforcement, providing grain refinement and strength improvement without significant cost increase

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The invention changes the chemical composition parameters of the flux core by incorporating specific mixed salts and rare earth elements (0.1-1.0 wt%). These compositional changes enable in-situ particle generation and grain refinement, achieving cost-effective weld reinforcement

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If additional reinforcement particles are added to welding material, then grain refinement is achieved, but wettability between particles and matrix deteriorates

Engineering Contradiction:
Improvegrain refinementVSAvoidbonding strength
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

Rare earth elements (such as Ce, La, Nd) serve as intermediaries between the flux core and weld metal matrix. These elements improve the wettability and interfacial bonding between the in-situ generated particles and the aluminum alloy matrix, ensuring reliable grain refinement without bonding deterioration

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The flux core is designed as a composite material system containing mixed salts and rare earth elements. This composite structure ensures that the in-situ generated particles have good interfacial compatibility with the weld metal, achieving both grain refinement and strong bonding

Inventive Principle:
Principle #40Composite materials

3Productivity

If flux-cored welding wire is used for 7XXX aluminum alloy welding, then welding efficiency is improved, but hot cracking tendency increases

Engineering Contradiction:
Improvewelding efficiencyVSAvoidhot cracking tendency
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The invention extracts harmful elements (such as excessive Cu, Fe, Si) that cause hot cracking from the flux core composition, while retaining beneficial mixed salts and rare earth elements. This selective removal reduces hot cracking tendency while maintaining welding efficiency

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The flux-cored welding process, which normally causes severe hot cracking in 7XXX aluminum alloys, is transformed into a beneficial process by using in-situ particle generation to refine grains and suppress dendritic growth. The same thermal input that causes cracking is converted into a grain-refining mechanism through controlled particle formation

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces hot cracking tendency, enhances the strength and mechanical performance of welded joints, and ensures chemical composition and corrosion resistance, leading to high-strength and aesthetically pleasing welds with reduced production costs.

Implementation Method 1

a reaction between the mixed salt and a welding base metal is directly induced through welding heat to produce in situ nanoparticles

Methodology Applied
Scientific EffectIn-situ reaction: Chemical Bonding

Implementation Method 2

dendrites in welds undergo equiaxed crystallization to effectively refine grains

Methodology Applied
Scientific EffectEquiaxed crystallization: Crystallisation

Implementation Method 3

a rare earth element is added to significantly refine grains

Methodology Applied
Scientific EffectGrain refinement: Crystallisation

Data Source

PatentUS12042885B1Aluminum alloy flux-cored welding wire and fabrication method thereof
Publication Date: 2024.07.23 JIANGSU UNIV
  • US12042885B1 patent drawing
  • US12042885B1 patent drawing
  • US12042885B1 patent drawing

AI summary

An aluminum alloy flux-cored welding wire and a fabrication method thereof are provided. In the present disclosure, a mixed salt is used as a filler for the flux-cored welding wire, and a reaction between the mixed salt and a welding base metal is directly induced through welding heat to produce in situ nanoparticles, which not only reduces a production cost of the welding wire, but also enhances the bonding between the added particles and the base metal through the prominent wettability between the in-situ enhancement particles and the base metal; and a rare earth element is added to significantly refine grains, which provides a new idea for the selection of a flux-cored welding wire for 7XXX aluminum alloy welding.