Self-Shielded Flux-Cored Wire Composition for Low-Hydrogen Welding

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Solution Overview

Problem

The self-shielded arc welding method has not been widely adopted due to difficulties in designing welding materials that balance welding workability, mechanical properties, pore resistance, cracking resistance, and reduced diffusible hydrogen content, as the components in the flux-cored wire interact complexly, affecting each other's performance.

Innovation Solution

A flux-cored wire with specific component content ranges, including F, Li, acid-soluble Al, Mg, S, CO2, Ba, Ca, Sr, REM, P, C, Mn, Ni, and Cu, formulated to satisfy certain mathematical formulas, ensuring excellent welding workability, low diffusible hydrogen content, and enhanced tensile strength and toughness of the weld metal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the flux-cored wire contains multiple components (BaF2, Sr composite oxide, Mg, C, Mn, Al, Ni, Mo) to improve welding workability and protection, then the protection effect and welding performance are enhanced, but the design complexity and difficulty in balancing component interactions increase

Engineering Contradiction:
Improveprotection effectVSAvoiddesign complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent specifies precise compositional ranges for each component (BaF2: 6.5-11.0%, Sr composite oxide: 3.0-5.0%, Mg: 1.0-3.0%, C: 0.02-0.07%, Mn: 0.5-2.0%, Al: 1.0-2.5%, Ni: 1.6-3.0%, Mo: 0.3-0.8%) to optimize the protective effect while managing component interactions. This parameter optimization resolves the contradiction by providing clear design guidelines that ensure reliable protection without excessive complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite flux composition combining multiple protective components (BaF2, Sr composite oxide, Mg) with alloying elements (C, Mn, Al, Ni, Mo) in specific proportions. This composite approach enhances the overall protection effect by leveraging the synergistic interactions among components while maintaining manageable design complexity through defined compositional ranges.

Inventive Principle:
Principle #40Composite materials

2Strength

If the flux-cored wire contains C, Mn, Ni, and other alloying elements to improve mechanical properties of weld metal, then the strength and toughness are enhanced, but the diffusible hydrogen content increases which deteriorates cracking resistance

Engineering Contradiction:
Improvemechanical propertiesVSAvoidcracking resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent carefully controls the content of alloying elements that affect both strength and hydrogen content. By specifying narrow ranges for C (0.02-0.07%), Mn (0.5-2.0%), Al (1.0-2.5%), and other elements, the patent optimizes the balance between achieving adequate mechanical properties and minimizing diffusible hydrogen content to prevent cracking.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts potentially harmful effects of alloying elements by using deoxidizing components (Mg: 1.0-3.0%, Al: 1.0-2.5%) that not only contribute to mechanical properties but also reduce oxygen and hydrogen content in the weld metal. This transforms elements that could increase hydrogen content into beneficial components that simultaneously improve strength and reduce cracking risk.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of operation

If the flux-cored wire uses traditional shielded metal arc welding material (rod-shaped, tens of centimeters) to maintain simplicity and wind resistance, then the device simplicity and outdoor usability are improved, but the working efficiency and automation capability deteriorate due to intermittent operation

Engineering Contradiction:
Improvedevice simplicityVSAvoidworking efficiency
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent divides the welding material into two functional parts: a steel outer sheath providing structural integrity and simplicity, and an internal flux core providing protective functions. This segmentation allows the wire to be continuously supplied like gas-shielded welding material while maintaining the simplicity and wind resistance characteristics of traditional self-shielded materials.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The flux-cored wire structure combines the advantages of both shielded metal arc welding (simplicity, wind resistance) and gas-shielded welding (continuous operation, automation capability). The wire can be continuously fed while providing self-shielded protection, making it universally applicable for both manual and automated welding processes.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Productivity

If the flux-cored wire uses gas-shielded arc welding material (single wire, several kilograms to tens of kilograms) to improve working efficiency and automation capability, then the continuous operation is achieved, but the wind resistance deteriorates since shielding gas is easily disturbed by wind

Engineering Contradiction:
Improveworking efficiencyVSAvoidwind resistance
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The flux-cored wire is self-shielding, meaning it contains all necessary protective components within its structure (BaF2, Sr composite oxide, Mg, and other flux components). The wire generates its own protective atmosphere through decomposition of these components during welding, eliminating dependence on external shielding gas that would be vulnerable to wind disturbance.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The wire achieves excellent welding workability, low diffusible hydrogen content, and improved pore and cracking resistance, with optimized tensile strength and toughness of the weld metal, addressing the previous design challenges.

Implementation Method 1

the flux contains, in mass % relative to a total mass of the wire, BaF2: 6.5% to 11.0%, a Sr composite oxide: 3.0% to 5.0%, and Mg: 1.0% to 3.0%

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 2

components that protect a molten metal from the atmosphere

Methodology Applied
Scientific EffectSlag formation:

Implementation Method 3

a voltage between a welding material and a base metal by a welding power supply

Methodology Applied
Scientific EffectArc heating: Electric Arc

Data Source

PatentUS11318567B2Flux-cored wire
Publication Date: 2022.05.03 KOBE STEEL LTD
  • US11318567B2 patent drawing

AI summary

In this flux-cored wire, the contents of F, Li, acid-soluble Al, Mg, S, CO2, Ba, Ca, Sr, REM, P, C which is not derived from a carbonate, Mn, Ni, and Cu are set to fall within prescribed ranges with respect to the total mass of the wire, and the blending ratio among these components is set to fall within a particular range.