Flux-Cored Wire Composition for Offshore Welding Toughness

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Solution Overview

Problem

Conventional flux-cored wires for all-position welding struggle to achieve a balance between high-temperature cracking resistance, low-temperature cracking resistance, and low-temperature toughness, particularly in large structures like offshore structures.

Innovation Solution

A flux-cored wire for gas-shielded arc welding with a steel outer sheath filled with a flux, comprising specific compositions such as TiO2, Si, C, Mn, Mo, Ni, Mg, F, K, Na, B, and Fe, with restricted contents of Ti, Al, V, and other elements, to optimize weld metal properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional flux-cored wire for all-position welding is used, then welding efficiency is improved, but the weld metal has high oxygen content resulting in poor low-temperature toughness

Engineering Contradiction:
Improvewelding efficiencyVSAvoidlow-temperature toughness
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the flux core, specifically controlling TiO2 content at 3-8 mass%, Si content at 0.1-0.5 mass%, C content at 0.01-0.15 mass%, and Mn content at 0.5-3.0 mass%. These parameter adjustments optimize the weld metal chemistry to achieve both high welding efficiency and improved low-temperature toughness by reducing oxygen content while maintaining productivity.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If flux-cored wire is designed for all-position welding, then versatility is improved, but it becomes difficult to achieve high-temperature cracking resistance, low-temperature cracking resistance, and low-temperature toughness simultaneously

Engineering Contradiction:
Improveall-position welding capabilityVSAvoidcracking resistance and toughness
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent creates a composite flux composition combining multiple materials with complementary functions: TiO2 (3-8 mass%) for slag formation and deoxidation, Si (0.1-0.5 mass%) for viscosity control and deoxidation, C (0.01-0.15 mass%) for reducing oxygen content, Mn (0.5-3.0 mass%) for strengthening and deoxidation, Mo (0.01-0.80 mass%) for high-temperature strength, Ni (1-3 mass%) for toughness, Mg (0.2-1.0 mass%) for deoxidation, F compounds (0.01-0.400 mass%) for hydrogen removal, K compounds (0.01-0.400 mass%) for arc stability, Na compounds (0.005-0.400 mass%) for slag fluidity, and B (0.001-0.005 mass%) for grain boundary strengthening. This composite approach enables all-position welding while achieving comprehensive cracking resistance and toughness.

Inventive Principle:
Principle #40Composite materials

3Strength

If the composition of flux-cored wire is optimized for strength, then yield strength is improved, but low-temperature toughness deteriorates

Engineering Contradiction:
Improveyield strengthVSAvoidlow-temperature toughness
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent optimizes the balance between strength and toughness by precisely controlling alloying element parameters: C content at 0.01-0.15 mass% provides sufficient strength without excessive hardening, Mn content at 0.5-3.0 mass% offers strengthening through solid solution and precipitation hardening while maintaining ductility, Mo content at 0.01-0.80 mass% enhances high-temperature strength and hardenability, and Ni content at 1-3 mass% improves toughness and resistance to brittle fracture. This parameter optimization achieves yield strength of 620 MPa or more while maintaining Charpy impact value at -60°C of 27 J or more.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10569369B2Wire containing flux for gas shield arc welding
Publication Date: 2020.02.25 KOBE STEEL LTD

AI summary

A flux-cored wire for gas-shielded arc welding has a steel outer sheath filled with a flux. The flux-cored wire includes specific amounts, relative to a total mass of the wire, of TiO2, at least one of Si, an Si oxide and an Si compound, C, Mn, Mo, Ni, at least one of metal Mg and an Mg alloy, an F compound, a K compound, an Na compound, B and a B compound, and Fe, respectively. A total content of each of Ti and a Ti alloy, metal Al and an Al alloy, and V is restricted to the specific range, respectively. A content of Ti is also restricted to the specific range relative to the total mass of the steel outer sheath.