Flux Composition for Soldering Wetting and Dewetting Control

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Solution Overview

Problem

Conventional fluxes with dimer acids exhibit varying wetting and spreading properties due to differences in carbon atoms and unsaturation levels, leading to inconsistent soldering finishes and potential dewetting issues across different heat histories.

Innovation Solution

A flux comprising 0.5 wt % to 20 wt % of dimer or trimer acids derived from oleic and linoleic acids, along with hydrogenated variants, combined with rosin, solvent, organic acids, amines, and thixotropic agents, to enhance wetting, spreading, and suppress dewetting.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional fluxes use dimer acids with varying carbon atoms and unsaturation levels, then the flux can be manufactured with different properties, but the wetting and spreading properties become inconsistent and dewetting occurs

Engineering Contradiction:
Improveflux property variationVSAvoidwetting and spreading consistency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent specifies precise parameter ranges for dimer acid composition (0.5-20 wt%) and restricts the types of monocarboxylic acids used in dimerization to those with 10-20 carbon atoms and specific unsaturation levels. This parameter control ensures consistent wetting and spreading properties while maintaining manufacturing flexibility within defined boundaries.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The flux comprises a composite formulation combining dimer acids (from specific monocarboxylic acid dimerization) with trimer acids and hydrogenated variants. This composite approach balances the reactive properties needed for metal oxide removal with the stability required to prevent dewetting, achieving both versatility and reliability.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If dimer acid structure varies due to different degree of unsaturation, then the chemical properties change, but the soldering finish quality becomes unstable

Engineering Contradiction:
Improvedimer acid varietyVSAvoidsoldering finish quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent defines specific parameter ranges for the monocarboxylic acids used in dimerization: 10-20 carbon atoms and controlled unsaturation levels. By constraining these parameters, the invention maintains manufacturing flexibility in producing different dimer acids while ensuring they all deliver stable soldering finishes within the specified composition range.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies local quality control by specifying particular properties for the dimer acid components (carbon atom count, unsaturation level) while allowing variation in other aspects. This enables manufacturers to produce dimer acids with different local characteristics (from different starting acids) while maintaining overall consistent soldering performance through the controlled composition range.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The flux ensures consistent wetting and spreading even under high thermal loads, effectively preventing dewetting and providing a stable soldering finish across various heat histories.

Implementation Method 1

a flux used for soldering chemically removes a metal oxide present on a solder and the metal surface of a joining object to be soldered

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

the solder wets and spreads well and the occurrence of dewetting can be suppressed

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentUS10857630B2Flux and solder paste
Publication Date: 2020.12.08 SENJU METAL IND CO LTD
  • US10857630B2 patent drawing
  • US10857630B2 patent drawing
  • US10857630B2 patent drawing

AI summary

Provided are a flux having improved wetting and spreading properties and capable of suppressing the occurrence of dewetting and a solder paste using this flux. The flux includes a total amount of 0.5 wt % or more and 20 wt % or less of: any of a dimer acid which is a reaction product of oleic acid and linoleic acid, a trimer acid which is a reaction product of oleic acid and linoleic acid, a hydrogenated dimer acid obtained by adding hydrogen to a dimer acid which is a reaction product of oleic acid and linoleic acid, or a hydrogenated trimer acid obtained by adding hydrogen to a trimer acid which is a reaction product of oleic acid and linoleic acid; or two or more of a dimer acid which is a reaction product of oleic acid and linoleic acid, a trimer acid which is a reaction product of oleic acid and linoleic acid, a hydrogenated dimer acid obtained by adding hydrogen to a dimer acid which is a reaction product of oleic acid and linoleic acid, and a hydrogenated trimer acid obtained by adding hydrogen to a trimer acid which is a reaction product of oleic acid and linoleic acid. The solder paste includes this flux and a metal powder.