Fly Ash Cementitious Material Rapid Setting Activator

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Solution Overview

Problem

There is a need for rapid-setting cementitious compositions that can facilitate quick repair of infrastructure such as roads and runways, especially in disaster scenarios, while minimizing material transport and costs, which existing technologies have not adequately addressed.

Innovation Solution

Rapid-setting cementitious materials are produced by mixing fly ash with an activator solution containing a silicate solution and a monovalent hydroxide, allowing for a final set time of no more than 65 minutes, and can be adjusted by varying the molarity of the hydroxide and the ratio of inert materials like sand, soil, or gravel to fly ash.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of time

If conventional cementitious materials are used for road and runway repair, then material strength can be achieved, but setting time is too long and material transport costs are high

Engineering Contradiction:
Improvesetting timeVSAvoidmaterial transport and logistics
Core Design Contradiction:
Loss of timeVSEase of manufacture

Solution Approach 1:

The cementitious material is divided into two separate components: dry fly ash (stored locally) and liquid activator solution (transported as needed). This segmentation allows the bulk material to be sourced locally while only the small-volume activator requires transport, reducing logistics costs and enabling rapid mixing on-site.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The fly ash is prepared in advance and stored in bulk at the repair location, while the activator solution is formulated with optimized composition (monovalent hydroxide concentration 0.5-2.0 M, silicate-to-hydroxide ratio 2-10) to achieve rapid setting. This preliminary preparation enables immediate mixing and setting when the activator is added, dramatically reducing setting time to 5-65 minutes.

Inventive Principle:
Principle #10Preliminary action

2Loss of time

If rapid-setting cementitious materials are developed, then setting time is reduced, but material composition complexity increases

Engineering Contradiction:
Improvefinal set timeVSAvoidactivator solution composition
Core Design Contradiction:
Loss of timeVSDevice complexity

Solution Approach 1:

The activator solution composition is optimized within specific parameter ranges: monovalent hydroxide concentration (0.5-2.0 M), silicate-to-hydroxide molar ratio (2-10), and pH (11-13). These controlled parameter changes enable rapid setting (5-65 minutes) while maintaining a relatively simple two-component system that balances performance with ease of use.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables rapid deployment and installation of pavement materials with compressive strengths of at least 550 psi within 24 hours, allowing for tailored set times and strengths to meet specific requirements, while reducing logistical challenges and costs.

Implementation Method 1

The activator solution when mixed with the fly ash produces a composition that has a final set time of no more than about 65 minutes

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS10800703B1Cementitious material
Publication Date: 2020.10.13 THE GOVERNMENT OF THE UNITED STATES AS REPRESENTED BY THE SECRETARY OF THE AIR FORCE
  • US10800703B1 patent drawing
  • US10800703B1 patent drawing
  • US10800703B1 patent drawing

AI summary

A rapid-setting composition includes fly ash and an activator solution for mixing with the fly ash. The activator solution has a silicate solution including a monovalent hydroxide. The activator solution when mixed with the fly ash produces a composition that has a final set time of no more than about 65 minutes.