Foam Barrier for CO2 Injection in Gravity Drainage

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Solution Overview

Problem

In gravity drainage/CO2 injection processes for tertiary oil recovery, premature breakthrough of CO2 occurs due to viscosity differences and heterogeneities in reservoirs, leading to reduced sweep efficiency and wasted injection fluid, as the carbon dioxide injection rate must be maintained below the critical gas injection rate to prevent viscous fingering.

Innovation Solution

Introducing a foaming surfactant solution and foaming gas to form a stable foam barrier at the CO2/crude oil interface, which prevents CO2 breakthrough by creating a physical barrier that can be swept into high-conductivity zones, allowing for increased CO2 injection rates without bypassing untreated areas, using gases with low solubility in both water and crude oil to maintain foam stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If CO2 injection rate is increased to improve productivity, then hydrocarbon recovery increases, but CO2 breakthrough occurs due to viscosity differences causing viscous fingering

Engineering Contradiction:
Improvehydrocarbon recovery rateVSAvoidCO2 breakthrough prevention
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces a foam barrier as an intermediary substance between the CO2 and crude oil. This foam barrier, formed by injecting foaming gas and surfactant solution, acts as a mediator that prevents direct CO2 breakthrough while allowing controlled displacement of crude oil. The foam stabilizes the interface and prevents viscous fingering, enabling higher CO2 injection rates without premature breakthrough.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical and chemical parameters at the CO2-crude oil interface by introducing surfactants and foaming agents. These parameter changes create a foam barrier with different interfacial tension properties, viscosity characteristics, and stability features that prevent CO2 breakthrough while maintaining displacement efficiency.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If CO2 injection rate is maintained below critical rate to prevent breakthrough, then sweep efficiency is maintained, but productivity is reduced due to wasted injection fluid

Engineering Contradiction:
Improvesweep efficiencyVSAvoidinjection fluid utilization
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The foam barrier serves as an intermediary that improves sweep efficiency by preventing CO2 bypass through high-permeability zones. The foam selectively blocks preferential flow paths while allowing CO2 to displace crude oil more uniformly, thereby improving sweep efficiency and reducing wasted injection fluid.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The foam barrier creates local quality changes in the reservoir by selectively blocking high-conductivity zones and preferential flow paths. This local modification of flow characteristics ensures more uniform CO2 distribution and improves sweep efficiency in previously bypassed areas.

Inventive Principle:
Principle #3Local quality

3Stability of the object's composition

If foaming gas with low solubility is used to maintain foam stability, then foam barrier stability increases, but gas selection constraints increase

Engineering Contradiction:
Improvefoam barrier stabilityVSAvoidgas selection flexibility
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent specifies parameter changes by selecting gases with low solubility in both water and crude oil. This parameter selection (low solubility) ensures foam stability by preventing gas dissolution that would collapse the foam structure. The surfactant concentration and foam quality are also adjusted as parameters to maintain stable foam barriers.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances crude oil production rates and sweep effectiveness by maintaining a stable foam barrier that prevents CO2 bypass, allowing for prolonged exposure of crude oil to supercritical CO2, resulting in increased hydrocarbon recovery and improved reservoir treatment uniformity.

Implementation Method 1

The foaming gas is introduced such that the surfactant solution and the foaming gas intimately intermingle and form barrier foam bubbles in the upper portion of the reservoir

Methodology Applied
Scientific EffectFoam: Foam

Implementation Method 2

CO2 at super/critical conditions is used for its favorable phase behavior characteristics with crude oil means, such as swelling, viscosity reduction, and reduced fluid-crude oil interfacial tension

Methodology Applied
Scientific EffectViscosity reduction:

Implementation Method 3

Mobilized, the crude oil flows downward in the reservoir towards the recovery wellbore. Such crude oil drainage occurs through a combination of both film flow, caused by interaction with and absorption of some of the super/critical CO2, and gravity drainage

Methodology Applied
Scientific EffectGravity drainage: Gravitation

Implementation Method 4

The foam barrier is positioned at an interface between the hydrocarbons to be treated in the reservoir and the CO2 cap

Methodology Applied
Scientific EffectPhysical barrier: Physical Containment

Data Source

PatentUS11668171B2Methodology to increase oil production rates in gravity drainage CO2 gas injection processes
Publication Date: 2023.06.06 SAUDI ARABIAN OIL CO
  • US11668171B2 patent drawing
  • US11668171B2 patent drawing
  • US11668171B2 patent drawing

AI summary

Described is a method for treating hydrocarbons in a reservoir. A foaming surfactant solution and a foaming gas are introduced into the upper portion of a reservoir such that barrier foam bubbles form. Then, super/critical carbon dioxide is introduced such that a CO2 cap forms. The CO2 cap is formed above a foam barrier of aggregated barrier foam bubbles positioned at an interface between hydrocarbons to be treated in the reservoir and the CO2 cap. The super/critical carbon dioxide is introduced into the reservoir at an injection rate that is greater than a pre-treatment critical gas injection rate. Hydrocarbons are recovered from a lower portion of the reservoir.