Foam-Forming Composition for Gas Well Liquid Unloading

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current methods for unloading liquids from gas wells and pipelines, such as intermitters, velocity strings, and chemical foamers, are inefficient and costly, especially in mature gas wells with high condensate-to-water ratios, as they either result in production losses or require significant capital expenditure.

Innovation Solution

A foam-forming composition comprising nonionic surfactants like alcohol ethoxylates and ionic surfactants like amphoteric surfactants is periodically injected into gas wells or pipelines to create a foam that effectively unloads liquids, with a weight ratio of nonionic to ionic surfactants ranging from 99/1 to 1/99, and optionally includes solvents and additional surface active agents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional chemical foamers are used to deliquify wells, then liquid unloading is achieved, but effectiveness decreases as condensate-to-water ratio increases

Engineering Contradiction:
Improveliquid unloading effectivenessVSAvoidperformance across varying condensate-to-water ratios
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the chemical parameters of the foamering composition by using a specific mixture of nonionic surfactants (alcohol ethoxylates with defined carbon chain and ethoxy group ranges) and ionic surfactants (amphoteric surfactants) in controlled ratios. This parameter optimization enables the foam to maintain effectiveness across varying condensate-to-water ratios, resolving the limitation of traditional foamers that lose effectiveness as condensate content increases.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite foamering composition combining multiple surfactant types (nonionic and ionic) with specific chemical properties. This composite approach creates a synergistic effect where the nonionic surfactants provide bulk foam stability and the ionic surfactants enhance liquid removal efficiency, together achieving reliable liquid unloading across diverse well conditions including high condensate-to-water ratios.

Inventive Principle:
Principle #40Composite materials

2Speed

If intermitters are used to prevent liquid loading, then gas velocity increases to unload liquids, but gas and condensate production is lost during off periods

Engineering Contradiction:
Improvegas velocityVSAvoidgas and condensate production
Core Design Contradiction:
SpeedVSProductivity

Solution Approach 1:

The patent enables continuous liquid unloading through continuous or periodic foam injection into the wellbore, eliminating the need for intermittent shut-in periods. The foam continuously reduces liquid loading while maintaining gas flow, thereby preserving gas and condensate production throughout the operation rather than losing production during off periods required by intermitter methods.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The foam acts as an intermediary substance that mediates between the gas flow and liquid loading problem. By injecting foam into the wellbore, the system creates a foam-driven flow regime that continuously unloads liquids without requiring the well to be shut in, thus maintaining continuous production while effectively managing liquid loading.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Speed

If velocity strings are inserted to increase linear gas velocity, then liquid loading is prevented, but production is lost due to string restriction

Engineering Contradiction:
Improvelinear gas velocityVSAvoidgas production
Core Design Contradiction:
SpeedVSProductivity

Solution Approach 1:

The patent replaces the mechanical velocity string restriction method with a chemical foam-based approach. Instead of using a physical string that restricts flow to increase velocity, the system injects foam that chemically and physically modifies the flow dynamics to achieve liquid unloading without mechanical restriction, thereby maintaining full gas production while preventing liquid loading.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The foam serves as an intermediary that enables liquid unloading without mechanical intervention. The foam injection system allows the well to operate at full capacity while the foam continuously removes liquids, eliminating the need for velocity strings that would otherwise restrict production to achieve sufficient gas velocity.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Stress or pressure

If additional compressor capacity is added to reduce wellhead pressure, then liquid loading is reduced, but large capital expenditure is required

Engineering Contradiction:
Improvewellhead pressureVSAvoidcapital expenditure
Core Design Contradiction:
Stress or pressureVSEase of manufacture

Solution Approach 1:

The patent employs a relatively inexpensive foamering composition that can be injected into the wellbore to achieve liquid unloading, replacing the need for expensive compressor capacity additions. The foam injection system provides a cost-effective alternative that addresses liquid loading issues without requiring significant capital expenditure on new compression infrastructure.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The foam acts as an intermediary substance that mediates the pressure and flow dynamics in the wellbore, providing liquid unloading functionality without requiring additional compressor capacity. The foam injection system offers a cost-effective solution that achieves wellhead pressure management and liquid removal without the large capital expenditure needed for extra compression infrastructure.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves superior liquid unloading performance compared to using surfactants alone, with the foam-forming method being effective in both cyclic and drive recovery methods under various conditions, enhancing liquid recovery from gas wells and pipelines.

Implementation Method 1

The invention relates to methods of using mixtures of nonionic surfactants and ionic surfactants to move liquid loads in gas wells and pipelines

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

creating a foam from the foam-forming composition, and then contacting the fluid in the well or pipeline with the foam and the gas to unload the fluid

Methodology Applied
Scientific EffectFoam: Foam

Data Source

PatentEP2115267B1High performance foams for unloading gas wells
Publication Date: 2019.04.03 BAKER HUGHES CO

AI summary

Mixtures of at least one nonionic surfactants and at least one ionic surfactant together with a gas create foams to aid the removal of produced hydrocarbon fluids from gas wells and pipelines. The foam-forming composition has superior performance in unloading liquids.