Polyurethane Foam Indicator Dye for Pass-Line Adhesion

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Solution Overview

Problem

Field failures in polyurethane foam articles, such as cracking, discoloration, and poor insulation, occur due to improper application techniques and quality issues, making it difficult to determine the root cause of failures and assign responsibility between suppliers and contractors.

Innovation Solution

Incorporating an indicator dye into the polyurethane foam system that changes color at specific temperatures, allowing for visual identification of issues such as inadequate cooling between lifts, thereby facilitating immediate rectification and accountability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If multiple lifts are spray applied in quick succession to achieve desired thickness, then productivity is improved, but the exotherm generated causes the lifts to discolor, split, scorch, burn, and inadequately adhere at pass-lines

Engineering Contradiction:
Improveapplication speedVSAvoidadhesion quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies a release agent to the substrate before spray-applying the first lift. This preliminary action prevents adhesion at the pass-line area, allowing the first and second lifts to be spray applied in quick succession without adhesion failures, thus resolving the contradiction between productivity and adhesion quality

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses a visual indicator (color change) to copy or represent the thermal state of the foam lifts. The indicator dye changes color based on temperature, providing visual feedback about the exotherm condition without requiring complex measurement equipment, enabling quick assessment of application quality

Inventive Principle:
Principle #26Copying

2Productivity

If the thickness of a lift exceeds 50 mm to reduce number of lifts, then productivity is improved, but the exotherm generated causes the lift to discolor, split, scorch, burn, and inadequately adhere to the substrate

Engineering Contradiction:
Improvenumber of liftsVSAvoidexotherm damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The release agent is applied beforehand to the substrate to create a non-adhesive zone. This allows thick lifts to be applied without the exotherm causing adhesion failures at the pass-line, as the release agent prevents bonding in that critical area

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The indicator dye changes color in response to temperature, providing visual warning when the exotherm reaches levels that could cause discoloration, splitting, or scorching. This allows operators to adjust application parameters to prevent damage while maintaining thick lift applications

Inventive Principle:
Principle #32Color changes

3Productivity

If lifts are spray applied without allowing the first lift to cool, then productivity is improved, but the exotherm generated during the second lift causes discoloration and adhesion failures at the pass-line

Engineering Contradiction:
Improvecooling timeVSAvoidpass-line integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The release agent is applied to the substrate before the first lift is spray applied. This preliminary protective action ensures that even when lifts are applied in quick succession without cooling, the pass-line area does not experience adhesion failures due to excessive exotherm

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The visual indicator provides real-time feedback on the thermal condition of the lifts. By copying the temperature state through color change, operators can immediately see if the exotherm is within acceptable ranges, enabling quick corrections to maintain pass-line integrity

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The color change indicator enables quick determination of field failure causes, preventing improper application techniques and improving the reliability of polyurethane foam articles by ensuring proper cooling and adhesion between lifts.

Implementation Method 1

The indicator dye chemically decomposes to impart a change in color in the first and second lifts and at the pass-line at a second temperature which is at or above the decomposition temperature of the indicator dye

Methodology Applied
Scientific EffectThermal decomposition: Decomposition (biological)

Implementation Method 2

the polyurethane foam article is formed from an exothermic reaction of an isocyanate-reactive resin composition and an isocyanate in the presence of a blowing agent

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Data Source

PatentUS9011966B2Polyurethane foam article and method of forming same
Publication Date: 2015.04.21 BASF SE
  • US9011966B2 patent drawing
  • US9011966B2 patent drawing
  • US9011966B2 patent drawing

AI summary

A polyurethane foam article comprises a first lift, a second lift, and a pass-line therebetween. The polyurethane foam article comprises the reaction product of an isocyanate-reactive resin composition, an isocyanate, and an indicator dye in the presence of a blowing agent. The indicator dye imparts a color in the first and second lifts and at the pass-line at a first temperature below a decomposition temperature of the indicator dye. The indicator dye chemically decomposes to impart a change in color in the first and second lifts and at the pass-line at a second temperature which is at or above the decomposition temperature of the indicator dye.