In Situ Foamed Cement for Loss Circulation Control

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Solution Overview

Problem

Current loss circulation treatments in wellbores face challenges in accurately addressing the dimensions and shapes of loss circulation zones, leading to inefficiencies and significant revenue losses due to fluid loss, as existing solutions are not adaptable to varying sizes and shapes of thief zones.

Innovation Solution

A non-hydraulic, foamed cementitious composition comprising magnesium oxide, a salt (such as magnesium chloride or sulfate), azodicarbonamide as a nitrogen gas-generating compound, carbohydrazide, and a foam surfactant, which forms a hard mass upon placement to fill and seal loss circulation zones effectively, regardless of their shape or size, without requiring extensive foam equipment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional loss circulation treatment materials are used, then fluid loss can be reduced in some zones, but they cannot adapt to varying sizes and shapes of thief zones leading to treatment inefficiency

Engineering Contradiction:
Improveadaptability to thief zone dimensionsVSAvoidtreatment efficiency
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The cement composition transitions from a fluid slurry state during injection to a solidified hard mass after placement, dynamically adapting its physical state to fill and seal thief zones of varying sizes and shapes. This phase change enables the material to conform to any loss circulation zone geometry while maintaining structural integrity for effective sealing.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The composition utilizes controllable setting time parameters and foam expansion ratios to adapt to different thief zone dimensions. By adjusting the foam-to-cement ratio and setting time, the treatment can be optimized for microfractures or large vugular zones, providing versatility across different loss circulation scenarios.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If foam equipment is used to create expandable foam treatments, then adaptability to thief zones improves, but equipment complexity and cost increase

Engineering Contradiction:
Improveform-filling capabilityVSAvoidfoam equipment requirements
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The composition generates its own foam structure through in-situ chemical reaction between the salt and water, eliminating the need for external foam generation equipment. The salt-water reaction produces foam bubbles that expand the cement slurry, allowing the material to self-foam and adapt to thief zone geometries without requiring complex foam generation systems.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces mechanical foam generation systems with a chemical foam generation mechanism. Instead of using mechanical foamers or pressurized foam equipment, the foam is generated through the chemical reaction between salt and water, substituting a complex mechanical system with a simpler chemical process.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Strength

If hydraulic cement is used for loss circulation control, then setting strength is achieved, but water sensitivity and solubility problems occur

Engineering Contradiction:
Improveset strengthVSAvoidwater stability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The composition creates a composite material system combining salt, water, foam, and cementitious components that together produce a water-stable, strong solid mass. The salt-water reaction products form a composite structure with the cement and foam, resulting in a material that achieves both strength and water stability, overcoming the limitations of conventional hydraulic cements in water-sensitive zones.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively forms a hard, stable seal within the wellbore to withstand hydrostatic pressures, reducing fluid loss and improving the adaptability of loss circulation treatments, thereby minimizing revenue losses and operational challenges.

Implementation Method 1

azodicarbonamide as a nitrogen gas-generating compound

Methodology Applied
Scientific EffectGas generation from azodicarbonamide decomposition: Decomposition (biological)

Implementation Method 2

Settable, non-hydraulic foamed cement compositions... forms a hard mass upon placement

Methodology Applied
Scientific EffectCement setting and hardening: Crystallisation

Data Source

PatentEP3743400B1Settable, form-filling loss circulation control compositions comprising in situ foamed non-hydraulic sorel cement systems and method of use
Publication Date: 2021.09.29 SAUDI ARABIAN OIL CO
  • EP3743400B1 patent drawingFigure 1~2
  • EP3743400B1 patent drawing

AI summary

This document relates to settable, non-hydraulic foamed cement compositions comprising nitrogen gas-generating compositions used for loss circulation control.