Foaming Adhesive Sheet Epoxy Acrylic Composition

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Solution Overview

Problem

Existing foaming adhesive sheets face challenges in achieving good blocking resistance, adhesiveness, and crack resistance, with previous methods requiring solvents for application and having limitations in handling and curing processes.

Innovation Solution

A composition comprising an epoxy resin with a softening temperature of 50°C or more and an epoxy equivalent of 5000 g/eq or less, combined with a second epoxy resin of higher softening temperature and weight-average molecular weight, and an acrylic resin with a weight-average molecular weight of 50,000 or more, to create a foaming adhesive sheet with improved properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a foaming adhesive sheet is used, then adhesiveness and crack resistance are improved, but blocking resistance deteriorates

Engineering Contradiction:
ImproveadhesivenessVSAvoidblocking resistance
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the molecular weight parameter of the acrylic resin to 50,000 or more, which fundamentally alters the adhesive composition's properties. This parameter change enables the adhesive to simultaneously achieve high adhesiveness and crack resistance while maintaining low blocking resistance, resolving the technical contradiction through precise control of molecular characteristics

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive system by combining epoxy resin with high molecular weight acrylic resin (50,000 or more) and specific foaming agents. This composite material approach allows the adhesive to exhibit multiple desirable properties simultaneously - high adhesiveness, crack resistance, and low blocking resistance - that cannot be achieved with single materials

Inventive Principle:
Principle #40Composite materials

2Reliability

If a foaming adhesive sheet is used, then adhesiveness and crack resistance are improved, but handling efficiency deteriorates

Engineering Contradiction:
Improvecrack resistanceVSAvoidhandling efficiency
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent specifies the acrylic resin molecular weight as 50,000 or more, which optimizes the balance between crack resistance and handling properties. This parameter control ensures the adhesive maintains appropriate viscosity and workability while achieving the desired crack resistance performance

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional adhesive methods are used, then application is simple, but solvent application and volatilization time are required

Engineering Contradiction:
Improveapplication simplicityVSAvoidsolvent volatilization time
Core Design Contradiction:
Ease of manufactureVSLoss of time

Solution Approach 1:

The patent extracts and eliminates the solvent component from the adhesive system by using a 100% solid composition of epoxy resin, acrylic resin, and foaming agent. This extraction of the solvent phase completely removes the volatilization step, allowing the adhesive to be applied and immediately activated without waiting for solvent evaporation

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent utilizes the phase transition of the foaming agent (from solid to gas) as the primary mechanism for adhesive activation and foam formation, replacing the evaporative phase transition of solvents. This substitution allows the adhesive to cure and expand in place without requiring solvent volatilization time

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a foaming adhesive sheet with enhanced blocking resistance, adhesiveness, and crack resistance, eliminating the need for solvents and improving handling efficiency, while maintaining high adhesiveness and crack resistance.

Implementation Method 1

a foaming agent, wherein a weight-average molecular weight of the acrylic resin is 50,000 or more

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Implementation Method 2

an epoxy resin, an acrylic resin compatibilized with the epoxy resin, a curing agent

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentUS20210332274A1Adhesive composition and foamable adhesive sheet
Publication Date: 2021.10.28 DAI NIPPON PRINTING CO LTD
  • US20210332274A1 patent drawing
  • US20210332274A1 patent drawing
  • US20210332274A1 patent drawing

AI summary

An adhesive composition including an epoxy resin, an acrylic resin compatibilized with the epoxy resin, a curing agent, and a foaming agent, wherein, as the epoxy resin, the adhesive composition includes a first epoxy resin with a softening temperature of 50° C. or more and an epoxy equivalent of 5000 g/eq or less, and a second epoxy resin with a softening temperature higher than the first epoxy resin and a weight-average molecular weight of 20,000 or more, and a weight-average molecular weight of the acrylic resin is 50,000 or more.