Foaming Composition Viscosity Control for Hollow Member Filling

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Solution Overview

Problem

Conventional foaming compositions for filling hollow members, such as automotive pillars, often result in insufficient filling properties due to shape-dependent performance, leading to incomplete filling and potential noise and vibration transmission.

Innovation Solution

A foaming composition comprising a polymer, organic peroxide, azodicarbonamide, and a (meth)acryloyl-group-containing compound, with specific viscosity and melt flow rate ranges, ensures stable foaming and excellent filling properties by controlling cross-linking and expansion ratios, thereby effectively filling complex shapes with minimal voids.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional foaming composition is used, then the filling process is simple, but the filling property is insufficient in complex hollow shapes

Engineering Contradiction:
Improvefilling propertyVSAvoidcomposition complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention changes the viscosity parameter of the foaming composition to a specific range (1050 to 4950 Pa·s at 120°C and 500 MPa) to achieve optimal filling properties. This parameter optimization allows the composition to properly fill complex hollow shapes while maintaining composition simplicity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite foaming composition containing polymer, organic peroxide, and azodicarbonamide in specific combinations. This composite material approach improves filling property by combining multiple functional components while keeping the overall composition relatively simple.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If viscosity is increased to improve filling, then expansion ratio decreases, but if viscosity is decreased for better expansion, then filling stability worsens

Engineering Contradiction:
Improvefilling stabilityVSAvoidexpansion ratio
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

The invention optimizes the viscosity parameter to a specific range (1050 to 4950 Pa·s) that balances filling stability and expansion ratio. This parameter change ensures the foam expands sufficiently while maintaining stable filling without excessive voids.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention achieves different local properties within the foam structure - high stability in regions requiring filling retention and adequate expansion in regions requiring volume increase. This is accomplished through the optimized viscosity range that allows differential behavior during the foaming process.

Inventive Principle:
Principle #3Local quality

3Reliability

If foaming composition is heated for stable foaming, then cross-linking occurs, but excessive cross-linking reduces flexibility

Engineering Contradiction:
Improvefoaming stabilityVSAvoidcross-linking degree
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention changes the heating parameters and composition formulation to achieve controlled cross-linking. The specific viscosity range and component ratios ensure that cross-linking occurs at an optimal level during heating, providing foaming stability while preventing excessive cross-linking that would reduce flexibility.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves reliable and satisfactory filling of hollow members with a foam that provides reinforcement, sound insulation, and vibration control, ensuring effective noise reduction and shape conformity.

Implementation Method 1

a foaming composition for filling containing ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, dicumyl peroxide, and azodicarbonamide is prepared, and heated to be foamed

Methodology Applied
Scientific EffectThermal decomposition: Pyrolysis

Implementation Method 2

a foaming composition for filling containing ethylene-vinyl acetate copolymer, ethylene-ethyl acrylate copolymer, dicumyl peroxide, and azodicarbonamide is prepared, and heated to be foamed

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Data Source

PatentUS8673423B2Foaming composition for filling, foaming member for filling, and foam for filling
Publication Date: 2014.03.18 NITTO DENKO CORP
  • US8673423B2 patent drawing
  • US8673423B2 patent drawing
  • US8673423B2 patent drawing

AI summary

A foaming composition for filling contains a polymer, an organic peroxide, and azodicarbonamide, and a viscosity thereof measured at a temperature of 120° C. and under a pressure of 500 MPa with a flow tester is in a range of 1050 to 4950 Pa·s.