Foaming Mold Uniform Cell Structure via Microcapsule Timing

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Solution Overview

Problem

Existing methods for producing foaming molds using thermally expandable microcapsules in injection molding fail to achieve a high expansion ratio and excellent appearance due to issues like surface roughness, distortion, and inadequate cell uniformity.

Innovation Solution

A method involving the use of thermally expandable microcapsules with a foaming starting temperature of 160 to 180°C and a die open delay period of 2 to 4 seconds, which allows for uniform expansion and suppression of foaming on the surface, resulting in a foaming mold with high expansion ratio and excellent appearance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If chemical foaming agents are used for injection molding, then foaming can be achieved, but the foaming agent decomposes rapidly in the molding machine and may not foam even after heating

Engineering Contradiction:
Improvefoaming reliabilityVSAvoidmolding process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the foaming mechanism from chemical decomposition to physical thermal expansion. By using thermally expandable microcapsules that expand at a specific temperature range (above melting point but below decomposition temperature of the resin), the patent achieves reliable foaming without the decomposition issues of chemical agents. The microcapsules are designed to expand only under controlled thermal conditions during molding.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces thermally expandable microcapsules as an intermediary between the resin and the foaming process. These microcapsules act as controlled gas sources that expand predictably under thermal stress, mediating the transformation from solid resin to foamed structure without the uncontrolled decomposition of chemical foaming agents.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If chemical foaming agents are used, then foaming can occur, but foaming residue and decomposed gas are generated that affect adhesion performance

Engineering Contradiction:
Improvefoaming volumeVSAvoidfoaming residue and decomposed gas
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent converts the harmful effect of rapid decomposition into a beneficial controlled expansion process. By using thermally expandable microcapsules that expand gradually at elevated temperatures, the patent eliminates the harmful residue and gas generation associated with chemical foaming agent decomposition, while still achieving the desired foaming volume.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The thermally expandable microcapsules serve as disposable gas sources that are consumed during the foaming process. Each microcapsule expands and ruptures to provide gas for cell formation, then is discarded, leaving no harmful residue. This approach replaces the problematic chemical foaming agents with clean, consumable microcapsules.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Manufacturing precision

If chemical foaming agents are used, then foaming can be achieved, but not all portions serve as closed cells since viscosity is low and foaming power exceeds melt tension, causing cell walls to tear

Engineering Contradiction:
Improvecell structure uniformityVSAvoidcell wall strength
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent changes the timing and control parameters of gas generation. By using thermally expandable microcapsules that expand after the resin has been injected and begun to cool, the patent ensures that gas is generated when the resin viscosity has increased enough to support cell wall formation. This temporal parameter change prevents cell wall tearing while achieving uniform closed-cell structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary resin injection and cooling before triggering the foaming action. By injecting the resin first and allowing it to cool and increase in viscosity, the patent creates a strong matrix that can support the subsequent gas expansion from microcapsules, preventing cell wall rupture and ensuring uniform closed-cell structure.

Inventive Principle:
Principle #10Preliminary action

4Strength

If injection molding is used with chemical foaming agents, then foaming can be achieved, but a cooling period is required before opening the die to increase viscosity

Engineering Contradiction:
Improveresin viscosityVSAvoidcooling period time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The patent maintains continuous useful action by overlapping the resin cooling process with the foaming process. Instead of separating cooling and foaming into distinct sequential steps, the patent allows foaming to occur during the cooling phase, eliminating idle time and maintaining productive action throughout the molding cycle.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent uses periodic thermal action to control the foaming process. By heating the resin to melt it for injection, then allowing it to cool to increase viscosity, and finally triggering microcapsule expansion during this cooling phase, the patent creates a periodic thermal cycle that optimizes both resin strength and foaming performance without extending the overall cycle time.

Inventive Principle:
Principle #19Periodic action

5Reliability

If thermally expandable microcapsules are used with injection molding, then foaming can occur, but satisfactory results are not obtained due to low expansion ratio, distortion, poor appearance, surface roughness, and foaming on the surface

Engineering Contradiction:
Improvefoaming qualityVSAvoidsurface finish and dimensional accuracy
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent optimizes multiple parameters simultaneously: microcapsule shell composition (nitrile-type monomer content), foaming agent content, heating temperature range, and die open timing. By adjusting these parameters, the patent achieves controlled expansion ratio, prevents surface foaming, eliminates distortion, and produces smooth surface finish while maintaining dimensional accuracy.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates different quality zones within the molded product. The skin layer near the mold cavity wall remains dense and non-foamed for smooth surface finish, while the interior core undergoes full foaming for lightweighting and insulation. This local differentiation of foaming quality resolves the contradiction between surface appearance and overall expansion ratio.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces foaming molds with uniform and closed cells, achieving a high expansion ratio, excellent mechanical strength, and improved appearance, suitable for applications such as home building materials and automobile components.

Implementation Method 1

a thermally expandable microcapsule which comprises: a shell polymer containing a homopolymer or a copolymer of ethylene unsaturated monomers containing 85% by weight or more of nitrile-type monomers; and a foaming agent containing 50% by weight or more of isooctane

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 2

a foaming agent containing 50% by weight or more of isooctane

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP1967345B1Molded foam article and method of producing molded foam article
Publication Date: 2019.08.07 SEKISUI CHEMICAL CO LTD
  • EP1967345B1 patent drawingFigure 1(a)~1(e)

AI summary

It is an object of the present invention to provide: a foaming mold having a high expansion ratio and a light weight and having an excellent appearance with no surface roughness; and a method for producing a foaming mold, whereby even in the case of using thermally expandable microcapsules for injection molding, the thermally expandable microcapsules can expand uniformly to give a foaming mold having a high expansion ratio and an excellent appearance. The invention is a foaming mold having uniform and closed cells, which has a cell diameter of 60 to 120 µm, a specific gravity of 0.6 g/ml or less, and a surface roughness of 4 µm or less.