Formic Acid Tack Solutions for Low VOC Paint Protection Film Installation

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Solution Overview

Problem

There is a need for improved solutions in paint protection film (PPF) installations to reduce the use of volatile organic compounds (VOCs) and minimize unpleasant odors, which are associated with common solvents like alcohols and acetic acid used in tack solutions.

Innovation Solution

The use of aqueous solutions containing formic acid, either as a tack solution or a combination slip/tack solution, to promote adhesion while minimizing VOC content and odor, with formic acid concentrations ranging from 0.1% to 10% by volume, and optionally including minor amounts of lower alcohols like isopropyl alcohol.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional solvents like alcohols and acetic acid are used in tack solutions, then adhesion promotion is effective, but VOC content and unpleasant odors increase

Engineering Contradiction:
Improveadhesion promotionVSAvoidVOC content and odor
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the tack solution by using formic acid (0.1-10% by volume) instead of traditional high-VOC solvents like alcohols and acetic acid. This parameter substitution maintains the adhesion-promoting function while significantly reducing VOC content and unpleasant odors, directly resolving the technical contradiction between effective adhesion and harmful emissions.

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If formic acid is used as the primary solvent in tack solutions, then VOC content and odor are reduced, but the effectiveness in promoting adhesion may be compromised

Engineering Contradiction:
ImproveVOC content and odorVSAvoidadhesion promotion
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent creates a composite tack solution formulation that combines formic acid (0.1-10% by volume) with water and optionally minor amounts of lower alcohols. This composite approach leverages the low-VOC advantage of formic acid while incorporating complementary ingredients that enhance adhesion promotion, ensuring both reduced harmful factors and maintained effectiveness.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the concentration parameter of formic acid within a specific range (0.1-10% by volume) to achieve the desired balance between reducing VOC content and maintaining adhesion effectiveness. This parameter optimization ensures that the formic acid concentration is sufficient to promote adhesion while remaining below levels that would create excessive odor or VOC issues.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If slip solution is applied to prevent film from sticking to itself, then film movement is facilitated, but adhesion to substrate is reduced

Engineering Contradiction:
Improvefilm movementVSAvoidadhesion to substrate
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies slip solution to the film surface as a preliminary action before mounting to prevent self-sticking and facilitate handling and positioning. Then, tack solution containing formic acid is applied to the substrate as a subsequent action to promote adhesion. This sequential application of different solutions with different functions resolves the contradiction between ease of operation and adhesion reliability.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses slip solution as an intermediary substance applied to the film surface to prevent premature adhesion during handling, while tack solution serves as an intermediary applied to the substrate to promote adhesion during mounting. These intermediary substances allow the film to transition from a non-adhesive state during handling to an adhesive state during installation, resolving the contradiction between ease of operation and adhesion reliability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Formic acid solutions effectively promote tack and adhesion, reducing the quantity of VOCs and odor, allowing for faster installation with less force required during squeegeeing and minimizing lift lines, while being less odorous than traditional solvents.

Implementation Method 1

reducing the surface tension of water, thereby promoting the ease of its removal via squeegeeing and very slightly beginning to dissolve the top most layer of adhesive

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Implementation Method 2

chemically drying the area by 'dissolving' the water and surfactant using alcohol (typically isopropyl alcohol)

Methodology Applied
Scientific EffectChemical dissolution: Solvation

Implementation Method 3

any remaining slip solution residue has evaporated

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS11840649B2Tack solutions and their use in applying films to substrates
Publication Date: 2023.12.12 EASTMAN PERFORMANCE FILMS LLC

AI summary

The present invention is directed to tack solutions comprising formic acid, and their use in applying adhesive-coated films to substrates. In particular, paint protection films (PPFs) can be applied to vehicle bodies using the solutions of the present invention.