Organic Light-Emitting Device Compound Formula 1 Blue Emission

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Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving high color purity, efficiency, and lifespan, particularly in blue emission materials.

Innovation Solution

A compound represented by Formula 1 is used in an organic light-emitting device, which includes a specific organic layer structure with a host and dopant configuration, enhancing the device's efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional emission materials (chelate complexes, coumarin derivatives, etc.) are used, then emission from visible range (blue to red) can be obtained, but color purity, efficiency, and lifespan need improvement

Engineering Contradiction:
ImprovelifespanVSAvoidefficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the molecular structure of emission materials by introducing specific substituents (R1-R9 groups including aryl, heteroaryl, and condensed polycyclic groups) at defined positions on the core structure. This systematic parameter change in molecular composition optimizes the balance between efficiency and lifespan, achieving both high quantum yield and improved device stability without sacrificing emission performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite emission layer structures combining the new compound (Formula 1) with host materials and dopants in specific weight ratios (e.g., 1:99 to 50:50). This composite approach integrates the advantages of different materials to achieve synergistic effects, simultaneously improving color purity, efficiency, and device lifespan

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If phenylanthracene derivatives are used as blue emission materials, then blue emission can be achieved, but color purity, efficiency, and lifespan require improvement

Engineering Contradiction:
Improvecolor purityVSAvoidlifespan
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent introduces specific functional groups and substituents at particular positions (R1-R9) on the phenylanthracene core structure. Each substituent placement is optimized to locally enhance specific properties: electron-donating groups improve efficiency, while sterically hindered groups at specific positions enhance stability and lifespan, achieving localized property optimization throughout the molecule

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention systematically varies molecular parameters including substituent types (aryl, heteroaryl, alkyl groups), substituent positions, and molecular weight through the defined R1-R9 groups. These parameter changes in the chemical structure directly correlate with improved color purity (narrower emission spectrum) and extended device operational lifetime

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic light-emitting device exhibits high color purity, high efficiency, and a long lifespan, particularly in blue emission, improving upon existing technologies.

Implementation Method 1

When a voltage is applied between the anode and the cathode, holes injected from the anode move to the emission layer via the hole transport layer, and electrons injected from the cathode move to the emission layer via the electron transport layer. Charge carriers such as holes and electrons recombine in an emission region to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS8987462B2Compound and organic light-emitting device comprising the same
Publication Date: 2015.03.24 SAMSUNG DISPLAY CO LTD
  • US8987462B2 patent drawing
  • US8987462B2 patent drawing
  • US8987462B2 patent drawing

AI summary

Provided are a compound of Formula 1 and an organic light-emitting device including the compound of Formula 1:The compounds of Formula 1 are particularly useful as fluorescent dopants in the emission layer of the organic light-emitting device.