Formula 1 Dispersant for Uniform Particulate Solid Distribution

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Solution Overview

Problem

Existing formulations for inks, paints, and plastics face challenges in uniformly dispersing particulate solids in both polar and non-polar organic media, as current dispersants are not effective across a wide range of organic mediums.

Innovation Solution

A composition comprising a particulate solid, an organic medium, and a compound of specific formula (1) and its salts, where the compound includes a hydrocarbyl chain, alkyleneoxy units, a dibasic acid or anhydride residue, and a polyamine or polyimine, which effectively disperses the particulate solid in various organic media, including water.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional dispersants are used, then dispersion in non-polar organic media may be achieved, but dispersion in polar organic media and water is poor

Engineering Contradiction:
Improvedispersion capability across different media typesVSAvoiduniformity of dispersion
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The dispersant molecule is designed with distinct functional regions: a polar head group (carboxylic acid, amine, or amide) for interacting with polar media and water, and a non-polar hydrocarbyl tail for interacting with non-polar organic media. This local differentiation of molecular properties enables the single dispersant to effectively stabilize particles in both polar and non-polar environments simultaneously.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The dispersant comprises a composite molecular structure combining different chemical functionalities (hydrocarbyl group, polar group, and optional polyether chain) into a single agent. This molecular composite allows the dispersant to exhibit dual compatibility with both polar and non-polar media, resolving the contradiction between adaptability and uniformity across different organic media types.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a single dispersant is designed for polar media, then dispersion in water and polar solvents improves, but dispersion in non-polar organic media deteriorates

Engineering Contradiction:
Improveuniformity of dispersion in polar mediaVSAvoideffectiveness across organic media range
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The dispersant molecule is designed with distinct functional regions: a polar head group (carboxylic acid, amine, or amide) for interacting with polar media and water, and a non-polar hydrocarbyl tail for interacting with non-polar organic media. This local differentiation of molecular properties enables the single dispersant to effectively stabilize particles in both polar and non-polar environments simultaneously.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The dispersant is designed as a universal agent that can function effectively across the entire spectrum of organic media (polar and non-polar) as well as water. The molecular structure combines polar and non-polar characteristics, allowing a single compound to perform the dispersion function in diverse media types without requiring separate dispersants for different applications.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If existing dispersants are used, then some level of dispersion is achieved, but uniform distribution and stability in formulations are insufficient

Engineering Contradiction:
Improvestability of formulationVSAvoiduniformity of particulate distribution
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The dispersant structure incorporates adjustable parameters including the length and branching of the hydrocarbyl chain (C1-50), the type of polar group (carboxylic acid, amine, or amide), and the presence of polyether chains with varying x values (0-60). By optimizing these structural parameters, the dispersant achieves enhanced uniformity of particulate distribution and improved formulation stability compared to conventional dispersants.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves excellent dispersion of particulate solids in a range of organic media, including polar and non-polar solvents, enhancing the uniformity and stability of formulations such as inks, paints, and plastics.

Implementation Method 1

a compound of Formula (1) and salts thereof... which effectively disperses the particulate solid in various organic media, including water

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

achieves excellent dispersion of particulate solids in a range of organic media, including polar and non-polar solvents

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentUS7767750B2Compositions
Publication Date: 2010.08.03 THE LUBRIZOL CORP
  • US7767750B2 patent drawing
  • US7767750B2 patent drawing
  • US7767750B2 patent drawing

AI summary

The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof; wherein R is C1-50-optionally substituted hydrocarbyl; Y is C2-4-alkyleneoxy; T is C2-4 alkylene; A is the residue of a dibasic acid or anhydride thereof; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof; x is from 2 to 60; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group RO—(Y)x-T-NH-A-. The invention further discloses the composition as a dispersant for an organic media.