Formula I Organometallic Compound for Saturated Color OLED Emission

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Solution Overview

Problem

Current organic light-emitting diodes (OLEDs) face challenges in achieving saturated colors for full-color displays, particularly in producing red, green, and blue pixels, and there is a need for materials that can efficiently emit light while maintaining cost-effectiveness and flexibility.

Innovation Solution

The development of a compound of Formula I, which includes specific organometallic structures, is used in the organic layer of OLEDs to enhance light emission properties, allowing for the creation of saturated colors and efficient light emission.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional organic materials are used in OLEDs, then cost-effectiveness and flexibility are maintained, but saturated color emission is difficult to achieve

Engineering Contradiction:
Improvecolor saturationVSAvoiddisplay performance quality
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent modifies the molecular structure of organometallic compounds by changing ligand types, metal centers, and molecular geometry to achieve saturated color emission. Specifically, the invention uses specific coordination geometries and ligand field adjustments to control the emission spectrum and achieve industry-standard saturated colors for display applications.

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If organometallic compounds are used to achieve saturated colors, then display performance is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecolor saturationVSAvoidfabrication complexity
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The patent divides the complex organometallic compound into modular components: specific ligand systems, metal centers, and coordinating groups. This modular approach allows for systematic synthesis and optimization of individual components before assembly, simplifying the overall manufacturing process while maintaining saturated color emission properties.

Inventive Principle:
Principle #1Segmentation

3Power

If conventional emission materials are used, then device simplicity is maintained, but light emission efficiency and color quality are insufficient

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidmaterial structure complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent employs composite organometallic materials combining specific ligand systems with metal centers to achieve high light emission efficiency and saturated colors. The composite structure integrates the advantages of organic ligands (flexibility, processability) with metal centers (efficient luminescence, color saturation), resolving the trade-off between performance and complexity.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enables OLEDs to produce high-quality, saturated colors, improving display performance while maintaining cost advantages and flexibility, suitable for various applications including full-color displays.

Implementation Method 1

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

One application for phosphorescent emissive molecules is a full color display

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS20240122059A1Organic electroluminescent materials and devices
Publication Date: 2024.04.11 UNIVERSAL DISPLAY CORP
  • US20240122059A1 patent drawing
  • US20240122059A1 patent drawing
  • US20240122059A1 patent drawing

AI summary

A compound of Formula I,is provided. In Formula I, one of Z1, Z2, and Z3 is N and the remainder are C; each of L1 and L2 is independently selected from a direct bond and a linking group; at least one of R1, R2, RA, RB, RC, RD, and RE comprises a group R* having a structure selected form the group consisting of Formula II, -Q(R3)(R4)a(R5)b, Formula III,and Formula IV,Each R, R′, R″, R1, R2, R3, R4, R5, RA, RB, RC, RD, RE, RF, RG, and RH is independently hydrogen or a General Substituent, with the proviso that group R* is not adamantyl. Formulations, OLEDs, and consumer products containing the compound are also provided.