Formula 1 Electrolyte Additive for High-Temperature Capacity Retention
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Solution Overview
Problem
Existing lithium secondary batteries face challenges with reduced output and increased resistance at high and low temperatures, require faster charging times, and have poor capacity retention in varying environments, necessitating improved electrolyte additives for enhanced performance.
Innovation Solution
An electrolyte additive with a specific compound structure, represented by Chemical Formula 1, is added to the battery electrolyte, reducing charging resistance, improving output, and enhancing capacity retention at high temperatures.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Power
If conventional electrolyte is used, then battery can operate, but charging resistance increases at high temperatures and output decreases
Solution Approach 1:
The patent introduces a novel electrolyte additive with specific molecular structure (Formula 1) containing phosphorus, sulfur, or arsenic atoms with specific bonding configurations. This chemical parameter change modifies the electrolyte's interaction with electrode surfaces, forming stable interface films that reduce charging resistance and improve power output, especially at high temperatures where conventional electrolytes fail.
Solution Approach 2:
The patent creates a composite electrolyte system by combining the new additive (Formula 1) with conventional electrolyte components. This composite approach leverages the unique properties of the phosphorus/sulfur/arsenic-containing compound while maintaining the base electrolyte's functionality, achieving synergistic effects that reduce resistance and improve power delivery.
2Productivity
If battery is designed for high output, then charging speed improves, but capacity retention deteriorates at high temperatures
Solution Approach 1:
The electrolyte additive in Formula 1 performs preliminary action by forming stable protective films on electrode surfaces before high-temperature operation begins. This pre-formed interface layer prevents degradation reactions during fast charging at high temperatures, preserving capacity retention while enabling high charging speeds.
Solution Approach 2:
The patent employs the additive as a cushioning agent that absorbs thermal stress and chemical degradation at the electrode-electrolyte interface before they can damage the battery's capacity. This beforehand protection mechanism allows the battery to withstand high-temperature fast charging without capacity loss.
3Power
If battery operates at high temperature, then power delivery improves, but lifespan decreases due to poor capacity retention
Solution Approach 1:
The electrolyte additive acts as a sacrificial component that consumes itself to form stable protective layers, allowing the main battery components to last longer. The additive decomposes preferentially to create stable interface films, sacrificing its own stability to protect the electrode structures from thermal degradation during high-temperature operation.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The electrolyte additive improves charging efficiency, reduces resistance, and extends the battery's lifespan and capacity retention, particularly at high temperatures, making it suitable for vehicle batteries.
Implementation Method 1
an electrolyte between a cathode and an anode enables smooth movement of lithium ions
Implementation Method 2
electricity is generated or consumed by oxidation-reduction reaction dependent on insertion and desorption at a cathode and an anode
Data Source
AI summary
The present invention relates to an electrolyte additive, a battery electrolyte including the electrolyte additive, and a secondary battery, and more particularly, to an electrolyte additive including a compound represented by Chemical Formula 1, an electrolyte including the electrolyte additive, and a secondary battery including the electrolyte. According to the present invention, due to low charging resistance, charging efficiency and output may be improved. In addition, the present invention has an effect of providing a secondary battery having a long lifespan and excellent capacity retention at high temperature.


