Amine Hole Transport Composition for Long-Life OLED Efficiency

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Solution Overview

Problem

Existing organic electroluminescence devices face challenges in reducing driving voltage, improving emission efficiency, and enhancing lifespan, necessitating the development of stable materials for these devices.

Innovation Solution

Incorporation of a specific amine compound represented by Formula 1 in the hole transport region of the organic electroluminescence device, which includes various substituents and linkages, enhancing the performance of the device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used in the hole transport region, then device structure is simple, but emission efficiency and lifespan are insufficient

Engineering Contradiction:
ImprovelifespanVSAvoidmaterial structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite material strategy by combining the amine compound (Formula 1) with other hole transport materials such as TPD, NPB, or TCTA in the hole transport region. This composite approach leverages the high hole mobility and stability of the amine compound while maintaining compatibility with existing device architectures, thereby extending lifespan without excessive complexity increase

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies molecular parameters of hole transport materials by introducing specific amine groups (Formula 1) with adjustable substituents (Ar1, Ar2, Ar3) and linkers (L1). This allows optimization of hole mobility, LUMO levels, and thermal stability parameters to achieve improved lifespan and emission efficiency while controlling material complexity

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional hole transport materials are used, then manufacturing is straightforward, but emission efficiency is low

Engineering Contradiction:
Improveemission efficiencyVSAvoidmaterial synthesis
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent optimizes emission efficiency by adjusting molecular parameters of the amine compound including substituent groups (Ar1, Ar2, Ar3) and linker types (L1). These parameter modifications enhance hole mobility and energy level alignment with emission layers, improving exciton formation and light emission efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The complex amine compound structure is segmented into functional modules: core amine group (Formula 1), substituent groups (Ar1, Ar2, Ar3), and linker units (L1). This segmentation allows independent optimization of each module for manufacturing ease while achieving high emission efficiency through their synergistic combination

Inventive Principle:
Principle #1Segmentation

3Reliability

If standard organic electroluminescence materials are used, then driving voltage is maintained at conventional levels, but lifespan and emission efficiency are insufficient

Engineering Contradiction:
ImprovelifespanVSAvoiddriving voltage
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent adjusts energy level parameters of the amine compound to optimize electron injection and hole transport. By modifying LUMO levels and hole mobility through substituent selection (Ar1, Ar2, Ar3) and linker types (L1), the material achieves better energy alignment with electrodes and emission layers, improving efficiency without excessive voltage increase

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality enhancement by positioning the amine compound specifically in the hole transport region where it provides localized improvement in hole mobility and stability. This targeted approach extends lifespan and efficiency without requiring system-wide voltage changes

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The amine compound improves the long-life characteristics and emission efficiency of the organic electroluminescence device, addressing the limitations of existing technologies.

Implementation Method 1

a hole transport region provided on the first electrode, an emission layer provided on the hole transport region

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Data Source

PatentUS12501825B2Organic electroluminescence device and amine compound for organic electroluminescence device
Publication Date: 2025.12.16 SAMSUNG DISPLAY CO LTD
  • US12501825B2 patent drawing
  • US12501825B2 patent drawing
  • US12501825B2 patent drawing

AI summary

An organic electroluminescence device of an embodiment includes a first electrode, a hole transport region on the first electrode, an emission layer on the hole transport region, an electron transport region on the emission layer, and a second electrode on the electron transport region, wherein the hole transport region includes an amine compound represented by Formula 1, thereby showing long life: