Four-Component Refrigerant Composition for Low-GWP Cooling Systems

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Solution Overview

Problem

Current refrigerants like R410A have high global warming potential (GWP), necessitating the development of low-GWP alternatives for air conditioning systems.

Innovation Solution

A refrigerant composition comprising trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), 1,3,3,3-tetrafluoropropene (R1234ze), and carbon dioxide (CO2), which offers a balance of low GWP and high refrigerating capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If R410A is used as refrigerant, then refrigerating capacity is maintained, but global warming potential increases

Engineering Contradiction:
Improveglobal warming potentialVSAvoidrefrigerating capacity
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent applies composite refrigerant formulation by combining multiple components (HFO-1132(E), R32, R1234ze, and CO2) in specific proportions to create a mixed refrigerant that achieves low GWP while maintaining adequate refrigerating capacity. This composite approach allows the refrigerant mixture to balance environmental performance with cooling effectiveness

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies refrigerant composition parameters by selecting specific components with low GWP characteristics and determining optimal concentration ranges for each component. By adjusting the compositional parameters within specified ranges, the refrigerant achieves the dual goal of reduced environmental impact and maintained refrigerating capacity

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If R32 is used to reduce GWP, then global warming potential decreases, but refrigerating capacity becomes insufficient

Engineering Contradiction:
Improveglobal warming potentialVSAvoidrefrigerating capacity
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent enhances R32 by formulating it as part of a composite refrigerant mixture containing HFO-1132(E), R1234ze, and CO2 in specific proportions. This composite formulation compensates for R32's insufficient refrigerating capacity while maintaining its low GWP advantage, achieving a balance between environmental performance and cooling effectiveness

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent merges R32 with other refrigerant components (HFO-1132(E), R1234ze, and CO2) to create a synergistic mixture. The combination allows the low-GWP characteristics of R32 to be preserved while the collective mixture provides enhanced refrigerating capacity that neither component could achieve alone

Inventive Principle:
Principle #5Merging (Combining)

Data Source

PatentUS12291665B2Composition containing refrigerant, use of same, refrigerator having same, and method for operating said refrigerator
Publication Date: 2025.05.06 DAIKIN INDUSTRIES LTD
  • US12291665B2 patent drawing
  • US12291665B2 patent drawing
  • US12291665B2 patent drawing

AI summary

An object is to provide a novel low-GWP mixed refrigerant.Provided as a means for a solution is a composition comprising a refrigerant, the refrigerant comprising trans-1,2-difluoroethylene (HFO-1132(E)), difluoromethane (R32), 1,3,3,3-tetrafluoropropene (R1234ze), and carbon dioxide.