Framed Proton-Conducting Membrane Bonding Without Adhesive Migration

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Solution Overview

Problem

The migration of adhesive into the active surface of a proton-conducting membrane in fuel cells deactivates its ionic conductivity and wetting of precious metal catalysts, leading to degradation mechanisms.

Innovation Solution

A framed proton-conducting membrane is processed to create regions with varying adhesion forces, including a high-adhesion region for secure bonding and a low-adhesion region to prevent adhesive migration, using methods like plasma irradiation, electromagnetic radiation, or dewetting agents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If adhesive is applied to join the membrane to components, then bonding strength is improved, but adhesive migration into the membrane occurs causing deactivation

Engineering Contradiction:
Improvebonding strengthVSAvoidadhesive migration
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The frame surface is treated to create spatially differentiated adhesion properties: a first region with increased force of adhesion for secure bonding, and a second region with lesser force of adhesion to prevent adhesive migration into the membrane. This local differentiation allows simultaneous achievement of strong bonding and migration prevention.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The frame surface is divided into functionally distinct regions: a first region optimized for adhesion (e.g., plasma-treated area) and a second region optimized for adhesive barrier function (e.g., Teflon-coated area). This segmentation allows each region to perform its specific function without interfering with the other.

Inventive Principle:
Principle #1Segmentation

2Strength

If adhesive migration is prevented by increasing adhesion force across the entire surface, then bonding is improved, but adhesive still migrates into the membrane

Engineering Contradiction:
Improvebonding strengthVSAvoidmembrane functionality
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

Instead of uniformly increasing adhesion across the entire frame surface, the invention applies local quality enhancement only to the first region where bonding is needed. The second region maintains or receives reduced adhesion properties, creating a spatial gradient that prevents adhesive migration while preserving bonding strength in the functional area.

Inventive Principle:
Principle #3Local quality

3Object-affected harmful factors

If the adhesive barrier region is made large, then migration prevention is improved, but bonding area is reduced

Engineering Contradiction:
Improveadhesive migration preventionVSAvoidbonding area
Core Design Contradiction:
Object-affected harmful factorsVSArea of stationary object

Solution Approach 1:

The frame surface is segmented into two distinct functional zones with clearly defined boundaries. The first region provides adequate bonding area for securing the membrane to components, while the second region provides sufficient barrier area to prevent adhesive migration. This segmentation allows both regions to be optimized for their respective functions without compromising the other.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Prevents adhesive migration into the membrane, reducing degradation and ensuring secure bonding while maintaining proton conductivity and catalyst integrity.

Implementation Method 1

it may be advantageous for the at least one region of the frame to be processed by means of plasma irradiation and thus activated

Methodology Applied
Scientific EffectPlasma irradiation: Plasma

Implementation Method 2

it is possible for the at least one region of the frame to be processed with electromagnetic radiation, especially with light. It may be advantageous for the at least one surface of the frame to be irradiated with UV light or with IR radiation

Methodology Applied
Scientific EffectUV light irradiation: Light

Implementation Method 3

it may also be advantageous for the processing of the at least one surface of the frame to be done by heating

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS12500258B2Method for production and processing of a framed proton-conducting membrane
Publication Date: 2025.12.16 AUDI AG
  • US12500258B2 patent drawing

AI summary

A method for production and processing of a framed proton-conducting membrane for a fuel cell, comprises: providing of the proton-conducting membrane and a frame comprising at least two media ports inserting the membrane into a recess of the frame, processing of at least one surface of the frame such that a first region exists with an increased force of adhesion for a joining by means of gluing, and at least one second region exists with a lesser force of adhesion than the increased force of adhesion.