Freeze-Protected Water-Based Adhesive for Sub-Zero Roofing

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Solution Overview

Problem

Water-based adhesives used in waterproofing applications are not freeze-resistant and cannot be applied at temperatures below 0°C, limiting their use in cold weather conditions, and they require a minimum application temperature of 5°C for safe application and drying, which is a challenge for substrates with low moisture absorption capacity.

Innovation Solution

A two-component water-based composition comprising an aqueous polymer dispersion, a metal salt, a liquid organic freeze point depressant, and a hydraulic binder, which allows for effective adhesion, sealing, or coating at temperatures below 0°C, including −10°C, without the need for special application apparatuses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water-based adhesives are used for bonding roofing membranes, then environmental and health safety is improved, but freeze resistance and applicability at sub-zero temperatures deteriorates

Engineering Contradiction:
Improveenvironmental and health safetyVSAvoidapplication temperature range
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

The patent modifies the chemical composition parameters of the adhesive by incorporating specific additives (ethylene glycol, propylene glycol, calcium formate, sodium formate) that change the freezing point and drying characteristics of the water-based formulation, enabling application at temperatures as low as -10°C while maintaining environmental safety

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite adhesive system combining water-based polymer dispersion with multiple functional additives including freeze point depressants, drying agents, and stabilizers, achieving both environmental compatibility and cold-weather performance

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If water-based adhesives are used on substrates with limited moisture absorption capacity, then environmental safety is improved, but drying speed and curing efficiency deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoiddrying speed
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent introduces hygroscopic substances (calcium chloride, calcium formate, sodium formate) as intermediary agents that actively absorb moisture from the adhesive film, facilitating rapid drying even on substrates with low moisture absorption capacity while maintaining the water-based environmentally safe formulation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The adhesive composition is modified by adding specific drying agents and hygroscopic salts that change the moisture transfer parameters, enabling efficient water removal from the adhesive layer through osmosis and capillary action rather than relying solely on substrate absorption

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If conventional water-based adhesives are applied at low temperatures, then environmental compatibility is maintained, but adhesion strength and bonding reliability deteriorates

Engineering Contradiction:
Improveenvironmental compatibilityVSAvoidadhesion strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent adjusts the polymer dispersion selection and formulation parameters to ensure proper film formation and adhesion at low temperatures, using polymers with appropriate glass transition temperatures and incorporating additives that maintain bonding effectiveness down to -10°C application conditions

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides a stable and efficient adhesive or sealant that can be stored and applied at sub-zero temperatures, ensuring proper drying and curing even on substrates with limited moisture absorption, thus extending the application window beyond traditional water-based adhesive limitations.

Implementation Method 1

a3) At least one liquid organic freeze point depressant D

Methodology Applied
Scientific EffectFreeze point depression: Freezing

Implementation Method 2

b1) A mineral binder composition C comprising at least one hydraulic binder H

Methodology Applied
Scientific EffectCapillary absorption: Capillary Action

Implementation Method 3

The roofing membrane can be mechanically fastened to the roof substrate... or it can be secured to the roof substrate by adhesive bonding

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS12195644B2Freeze protected water-based dispersion adhesive and use thereof
Publication Date: 2025.01.14 SIKA TECH AG
  • US12195644B2 patent drawing

AI summary

A two-component composition including a first component A including an aqueous dispersion of at least one polymer P, at least one metal salt M, and at least one liquid organic freeze point depressant D, and a second component B having a mineral binder composition C having at least one hydraulic binder H. The two-component composition is used as an adhesive, sealant or coating and to a method for bonding a first substrate to a second substrate.