Frequency Comb Downhole Chemical Sensing

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Solution Overview

Problem

Conventional spectroscopy methods for detecting chemicals downhole are inefficient due to high energy requirements, broad spectral signatures of liquids, and the challenge of maintaining coherent RF sources, leading to long measurement times and high costs.

Innovation Solution

The use of frequency combs in conjunction with coherent anti-Stokes Raman scattering (CARS) and fiber optics to generate high spectral resolution, allowing for the detection of chemicals with high sensitivity and fast acquisition of information, utilizing a frequency comb module with a beam splitter and low pass filter to analyze chemical samples downhole.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional spectroscopy methods are used for downhole chemical detection, then broad bandwidth and high energy are provided, but measurement time increases and cost increases

Engineering Contradiction:
Improvespectral resolutionVSAvoidmeasurement time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The frequency comb source segments the broadband spectrum into numerous narrow, evenly spaced spectral lines. This segmentation allows the system to achieve high spectral resolution through the individual comb lines while maintaining fast measurement speeds by capturing the entire comb spectrum simultaneously, resolving the contradiction between spectral resolution and measurement time.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the spectral parameters by using a frequency comb source with specific characteristics (narrow line width, high frequency stability, evenly spaced lines) compared to conventional broadband sources. This parameter change enables simultaneous achievement of high spectral resolution and fast acquisition by matching the comb properties to the CARS detection requirements.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If conventional spectroscopy uses large bandwidth and high energy, then different wavelengths are produced, but the system becomes expensive and difficult to implement downhole

Engineering Contradiction:
Improvespectral resolutionVSAvoidsystem complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical spectroscopy systems with an optical frequency comb source combined with CARS detection. This substitution eliminates the need for moving parts, complex wavelength tuning mechanisms, and large optical components, thereby reducing device complexity while maintaining high spectral resolution capability for downhole implementation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention transitions from conventional time-domain or mechanical wavelength-sweeping approaches to a frequency-domain approach using frequency combs. This dimensional change in the spectral domain allows simultaneous access to multiple wavelengths without mechanical movement, simplifying the overall system architecture for downhole deployment.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Measurement precision

If spectrum of chemicals in liquid form is measured, then chemical identification is achieved, but significant energy and time are required due to broad spectral signatures

Engineering Contradiction:
Improvedetection sensitivityVSAvoidenergy consumption
Core Design Contradiction:
Measurement precisionVSUse of energy by moving object

Solution Approach 1:

The patent changes the excitation parameters by using frequency-comb-resolved CARS, which provides narrow, well-defined spectral lines compared to conventional broadband excitation. This parameter change in the excitation spectrum enables more efficient energy coupling to specific molecular vibrations, reducing the total energy required while improving detection sensitivity for liquid chemicals.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate detection of liquid chemicals with high spectral resolution and sensitivity, reducing measurement time and costs by leveraging the high bandwidth and sensitivity of frequency combs in spectroscopic analysis.

Implementation Method 1

broadcasting a coherent light from a frequency comb module

Methodology Applied
Scientific EffectFrequency comb:

Implementation Method 2

The light may be used to capture the vibrational and rotational spectrum of molecules in the liquid phase

Methodology Applied
Scientific EffectCoherent light: Coherent Light

Implementation Method 3

The use of frequency combs in conjunction with coherent anti-Stokes Raman scattering (CARS)

Methodology Applied
Scientific EffectCoherent anti-Stokes Raman scattering:

Implementation Method 4

directing the coherent light through a fiber optic line to the interrogation device

Methodology Applied
Scientific EffectOptical fiber transmission: Optical Fibre

Data Source

PatentUS10738597B2Frequency comb for downhole chemical sensing
Publication Date: 2020.08.11 HALLIBURTON ENERGY SERVICES INC
  • US10738597B2 patent drawing
  • US10738597B2 patent drawing
  • US10738597B2 patent drawing

AI summary

The present disclosure relates to systems and methods for analyzing fluids. The method for analyzing a chemical sample within a wellbore, contained within an interrogation device, may comprise broadcasting a coherent light from a frequency comb module, directing the coherent light through a fiber optic line to the interrogation device, irradiating the chemical sample with the coherent light, capturing light resulting from the irradiation of the chemical sample, and producing a spectrum resulting from the captured light from the chemical sample. A frequency comb system for analyzing a chemical sample may comprise a frequency comb module configured to broadcast a coherent light and a fiber optic line that extends into a wellbore to an interrogation device. The interrogation device may further be configured to contain the chemical sample for irradiation by the coherent light. The frequency comb system may further comprise a receiver and an information handling system.