Friction Adjustment Interface for Nickel Alloy High-Temperature Sliding

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Nickel and nickel alloy components used in high-temperature applications, such as aeronautical ball joints, experience significant surface wear and galling due to poor friction behavior and sensitivity to scratching, especially at temperatures between 300° C. and 650° C., where existing coatings like WC-C:H become ineffective.

Innovation Solution

An adjustment interface comprising two layers is introduced: a first layer with a composition that forms a glaze-type protective oxide layer and a second layer acting as a catalyst for oxide stabilization, both deposited using thermal spray coating and thermochemical carbon diffusion, respectively, to reduce adhesive frictional wear and improve sliding properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If nickel or nickel alloy parts are used for high-temperature applications, then mechanical strength and oxidation resistance are improved, but friction behavior deteriorates with marked tendency for galling and high sensitivity to scratching

Engineering Contradiction:
Improvemechanical strength at high temperatureVSAvoidfriction behavior
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention applies a composite coating system consisting of multiple layers with different functions: a first layer (e.g., WC-C:H) providing hardness and scratch resistance, and a second layer (e.g., copper alloy) providing low friction and wear resistance. This composite structure combines the advantages of different materials to overcome the poor friction behavior of nickel alloys while maintaining their high-temperature strength.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the surface properties of the nickel alloy parts by applying coatings with different chemical compositions and physical properties. The coating layers have different hardness, friction coefficients, and thermal stability compared to the base nickel alloy, thereby improving the overall tribological performance at high temperatures.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If WC-C:H coating is used for low-temperature applications, then friction and wear resistance are improved, but effectiveness deteriorates at high temperatures above 250°C due to graphitization

Engineering Contradiction:
Improvefriction and wear resistanceVSAvoidoperating temperature range
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The invention creates a composite coating system where the WC-C:H layer is combined with a copper alloy layer. The copper alloy layer remains stable and effective at high temperatures where the WC-C:H layer would graphitize, compensating for its thermal instability and extending the operational temperature range.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The copper alloy layer acts as an intermediary between the WC-C:H coating and the nickel alloy substrate, providing thermal stability and maintaining low friction properties at high temperatures where the WC-C:H layer alone would fail.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If copper alloy coating is applied for low-temperature friction reduction, then sliding properties are improved, but effectiveness deteriorates above 250°C due to copper monoxide formation

Engineering Contradiction:
Improvesliding propertiesVSAvoidtemperature stability
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The invention combines copper alloy coating with WC-C:H coating in a composite structure. The WC-C:H layer provides thermal stability and structural support, while the copper alloy layer provides low friction properties. Together, they maintain effective sliding properties at temperatures where either material alone would fail.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention modifies the surface composition and structure by applying multiple coating layers with different thermal stabilities. This changes the overall temperature resistance parameter of the surface, enabling effective operation at higher temperatures than a single copper alloy coating could achieve alone.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If existing coatings are used at high temperatures between 300°C and 650°C, then some protective properties are maintained, but adhesive frictional wear and galling increase significantly

Engineering Contradiction:
Improveprotective propertiesVSAvoidadhesive frictional wear and galling
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention applies a multi-layer composite coating system where each layer contributes different protective properties. The combination of layers creates synergistic effects that reduce adhesive frictional wear and galling at high temperatures better than any single coating material could achieve alone.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention applies different coating materials with specific local properties to different layers of the surface treatment. The first layer provides hardness and scratch resistance, while the second layer provides low friction and wear resistance, creating locally optimized surface properties that collectively reduce adhesive wear and galling.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The interface significantly reduces adhesive frictional wear and galling, maintaining stable sliding properties and enabling easy dismantling, with a friction coefficient around 0.45 and minimal wear, effectively addressing the limitations of existing coatings at high temperatures.

Implementation Method 1

a first adjustment layer (4) deposited on one of the two parts and having a composition making it possible, with the friction with the other part, to form a glaze-type layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

a second adjustment layer (5) deposited on the second part for the purposes of cooperation with the first layer by making it possible to act as a catalyst for the oxide formed by friction with the first layer

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

The first adjustment layer is a layer of cobalt alloy, the cobalt content of which is at least 40%

Methodology Applied
Scientific EffectThermal spray: Plasma Spray

Implementation Method 4

The second adjustment layer is produced by thermochemical carbon diffusion treatment at the surface of the part

Methodology Applied
Scientific EffectCarbon diffusion: Diffusion

Data Source

PatentUS10113224B2Friction adjustment interface between two parts made of nickel or nickel or cobalt-chromium alloy that are in relative motion against one another at high temperature
Publication Date: 2018.10.30 AIRBUS OPERATIONS (SAS)
  • US10113224B2 patent drawing
  • US10113224B2 patent drawing
  • US10113224B2 patent drawing

AI summary

An adjustment interface inserted between a first part made of nickel or made of nickel alloy or made of cobalt-chromium alloy in relative motion with a second part made of nickel or made of nickel alloy or made of cobalt-chromium alloy. The interface includes a first adjustment layer on one of the two parts and has a composition that makes it possible, with the friction with the other part, to create a glaze-type layer. A second adjustment layer is deposited on the second part for cooperation with the first layer to act as a catalyst for the oxide formed by friction with the first layer. The first glaze layer of the interface improves the sliding of the parts under friction. The catalyst function provided by the second layer makes it possible to stabilize the oxide formed by friction and to thus ensure a lubrication function over an extended high-temperature range.