Friction Reducing Additives with Nanoparticles for Hydraulic Fracturing

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Solution Overview

Problem

Conventional hydraulic fracturing treatments in subterranean formations face energy losses due to friction, requiring high pressures and large amounts of fluid, which can lead to formation damage and inefficient fracture creation in low permeability formations.

Innovation Solution

The use of friction reducing additives comprising a combination of polymers and nanoparticles in treatment fluids, which interact to enhance viscosity and reduce friction, allowing for effective fracture creation with reduced energy input and minimal formation damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional friction reducing polymers are used in aqueous treatment fluids, then energy losses due to friction are reduced, but large amounts of polymer are required which increases cost and complexity

Engineering Contradiction:
Improveenergy loss due to frictionVSAvoidamount of polymer required
Core Design Contradiction:
Loss of energyVSQuantity of substance

Solution Approach 1:

The patent combines polymers with nanoparticles (such as silica, metal oxides, or carbon-based particles) to create composite friction reducing additives. This composite structure leverages the viscosity-modifying properties of polymers and the surface-active properties of nanoparticles, achieving enhanced friction reduction efficiency with lower concentrations of both components compared to conventional polymer-only additives.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes shear-thinning non-Newtonian fluid behavior by selecting polymers and nanoparticles that change viscosity under different flow conditions. The treatment fluid maintains higher viscosity at low shear rates for better fracture conductivity but reduces viscosity at high shear rates during pumping to minimize friction losses and energy requirements.

Inventive Principle:
Principle #35Parameter changes

2Power

If large amounts of water or fluids are pumped at high rates and pressures to create fractures, then sufficient energy is provided to form fractures of desired geometries, but formation damage and plugging may occur

Engineering Contradiction:
Improveenergy input for fracture creationVSAvoidformation damage and plugging
Core Design Contradiction:
PowerVSObject-affected harmful factors

Solution Approach 1:

The patent employs shear-thinning fluids that exhibit high viscosity at low shear rates to maintain fracture conductivity and low viscosity at high shear rates during injection to reduce pumping friction. This parameter change allows effective fracture creation with reduced energy input and minimizes formation damage by avoiding excessive shear stresses on formation particles.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The treatment fluid is designed with spatially varying properties: high viscosity in the fracture zone to maintain conductivity, and reduced viscosity in the wellbore during pumping to minimize friction. The polymer and nanoparticle concentrations can be optimized locally to achieve different rheological properties in different zones of the treatment system.

Inventive Principle:
Principle #3Local quality

3Productivity

If small size proppant is used with low viscosity fluid in slickwater treatments, then fractures can be created in low permeability formations, but considerable energy is lost due to friction between turbulent flow and formation/tubular goods

Engineering Contradiction:
Improvefracture creation effectiveness in low permeability formationsVSAvoidenergy loss due to turbulent flow friction
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent uses shear-thinning treatment fluids that transition from high viscosity at low shear rates (improving proppant suspension and transport in low permeability formations) to low viscosity at high shear rates (reducing friction losses during high-rate pumping). This dynamic parameter change resolves the contradiction between productivity and energy efficiency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The combination of polymers and nanoparticles creates a composite fluid system that enhances proppant suspension capability while maintaining low friction during pumping. The nanoparticles provide additional surface area for fluid structure formation, improving proppant carrying capacity without requiring high fluid viscosity throughout the entire flow path.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The additives achieve enhanced viscosity and friction reduction, enabling more efficient fracture stimulation with less polymer usage, reduced plugging, and effective conductivity maintenance in subterranean formations, even in challenging fluids like brines.

Implementation Method 1

the nanoparticles may interact or associate with molecules of the polymer (e.g., via hydrogen bonding, hydrophobic association, covalent bonding, ionic associations, etc.)

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Implementation Method 2

the nanoparticles may interact or associate with molecules of the polymer (e.g., via hydrogen bonding, hydrophobic association, covalent bonding, ionic associations, etc.)

Methodology Applied
Scientific EffectHydrophobic association: Hydrophobe

Implementation Method 3

introducing the treatment fluid into a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture

Methodology Applied
Scientific EffectHydraulic pressure: Pressure Increase

Data Source

PatentUS11505735B2Friction reducing additives including nanoparticles
Publication Date: 2022.11.22 HALLIBURTON ENERGY SERVICES INC
  • US11505735B2 patent drawing
  • US11505735B2 patent drawing

AI summary

Compositions and methods for use in fracturing treatments using friction reducing additives that include nanoparticles are provided. In some embodiments, the methods include: providing a treatment fluid that includes an aqueous base fluid and a friction reducing additive, the friction reducing additive including at least one polymer and a plurality of nanoparticles; and introducing the treatment fluid into a portion of a subterranean formation at or above a pressure sufficient to create or enhance at least one fracture in the subterranean formation.