Fischer-Tropsch Cable Fill Composition for Low Temperature Stability

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Solution Overview

Problem

Existing cable fill compositions for optical and electrical cables face challenges in processability, rheology, low temperature performance, color stability, and additive requirements, particularly in minimizing viscosity loss and discolouration at elevated temperatures.

Innovation Solution

A cable fill composition comprising Fischer-Tropsch derived base oil and a thickening system, preferably with a styrenic block copolymer, which improves rheology, processability, and low temperature properties while reducing the need for additives like antioxidants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional paraffinic oils are used in cable fill composition, then the composition provides basic filling and insulation properties, but the viscosity increases significantly at low temperatures and the composition loses stability at elevated temperatures

Engineering Contradiction:
Improvelow temperature propertiesVSAvoidprocessability
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters by using Fischer-Tropsch derived base oil instead of conventional paraffinic oils. This parameter change results in improved low temperature fluidity while maintaining thermal stability at elevated temperatures, resolving the contradiction between low temperature performance and overall processability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite cable fill composition by combining Fischer-Tropsch derived base oil with specific additives including pour point depressants and antioxidants. This composite approach achieves both improved low temperature properties and enhanced thermal stability, while maintaining good processability during manufacturing

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If cable fill composition is designed for low viscosity to improve ease of application, then the composition flows better during manufacturing, but the composition loses too much material in case of cable damage

Engineering Contradiction:
Improveease of applicationVSAvoidloss of composition
Core Design Contradiction:
Ease of manufactureVSLoss of substance

Solution Approach 1:

The patent introduces thixotropic properties to the cable fill composition, making the viscosity dynamic rather than static. The composition becomes less viscous under shear stress during application (improving ease of manufacture) but returns to higher viscosity at rest (reducing material loss upon cable damage). This dynamic viscosity adjustment resolves the contradiction between ease of application and material retention

Inventive Principle:
Principle #15Dynamics

3Stability of the object's composition

If antioxidants are increased to improve color stability at elevated temperatures, then the composition resists discolouration, but the complexity of the formulation increases and manufacturing becomes more difficult

Engineering Contradiction:
Improvecolour stabilityVSAvoidformulation complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent selects Fischer-Tropsch derived base oil which inherently possesses superior oxidation resistance and color stability compared to conventional base oils. This converts the potential harm of thermal oxidation into a benefit, as the base oil itself resists discolouration at elevated temperatures without requiring complex antioxidant formulations, thus resolving the contradiction between color stability and formulation simplicity

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits improved ease of manufacture, low viscosity loss at low shear rates, high flashpoint, and color stability, making it suitable for colder climates with reduced antioxidant requirements.

Implementation Method 1

a thickening system, wherein the thickening system comprises at least one block copolymer

Methodology Applied
Scientific EffectThickening:

Implementation Method 2

improved thixotropy... exhibits a lower viscosity at high shear rates which improves ease of manufacture and ease of application of the composition. It has also been found that the cable fill composition has a low effect on the viscosity of the composition at low shear rates which means low or no loss of composition in case of cable damage

Methodology Applied
Scientific EffectThixotropy: Thixotropy

Data Source

PatentUS10189975B2Cable fill composition
Publication Date: 2019.01.29 SHELL USA INC
  • US10189975B2 patent drawing

AI summary

A cable fill composition for an optical fiber cable, said cable fill composition comprising (i) a Fischer-Tropsch derived base oil; and (ii) a thickening system, wherein the thickening system comprises at least one block copolymer. The cable fill composition of the present invention provides improvements in rheological characteristics, low temperature properties, and colour stability properties, as well as minimizing the levels of additives such as antioxidants and pour point depressants which need to be used.