Fuel Additive Combination for Ice Prevention and Detergency

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Solution Overview

Problem

Existing fuel additives fail to effectively prevent the formation of ice flakes in diesel fuels at low temperatures without compromising the detergent properties or increasing costs, and existing anti-icing agents are either expensive or inhibit detergent performance.

Innovation Solution

A combination of polyalkylene glycol compounds and polyol esters is used to prevent ice flake formation in diesel fuels, maintaining detergent effectiveness and reducing additive costs, with a mass ratio of 10:1 to 1:10, effective at temperatures below -15°C.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional anti-icing additives (DIEGME, EGME, or alcohols) are used to prevent ice flake formation, then ice prevention effectiveness is improved, but either cost increases significantly or detergent properties are inhibited

Engineering Contradiction:
Improveice prevention effectivenessVSAvoiddetergent property inhibition
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention uses a composite additive system comprising a polyol ester (T1) combined with a polyalkylene glycol compound (T2) in specific ratios. This composite approach allows the polyol ester to provide ice prevention while the polyalkylene glycol compound maintains detergent properties, resolving the contradiction between ice prevention effectiveness and detergent functionality

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the chemical composition parameters by selecting specific polyol esters with particular molecular weights and acid values, and combining them with polyalkylene glycol compounds in controlled ratios. This parameter optimization enables simultaneous achievement of ice prevention and detergent effectiveness without using conventional additives that inhibit detergent properties

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional anti-icing additives (DIEGME, EGME) are used to prevent ice flake formation, then ice prevention effectiveness is improved, but additive cost increases

Engineering Contradiction:
Improveice prevention effectivenessVSAvoidadditive cost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention replaces expensive conventional anti-icing additives (DIEGME, EGME) with a cost-effective combination of polyol ester and polyalkylene glycol compound. This substitution maintains ice prevention effectiveness while significantly reducing additive costs, making the solution economically viable for widespread use

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Object-generated harmful factors

If detergent additives are added to maintain engine cleanliness, then engine cleanliness is improved, but ice flake formation is aggravated at low temperatures

Engineering Contradiction:
Improveengine cleanlinessVSAvoidice flake formation
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The polyalkylene glycol compound acts as an intermediary that bridges the conflicting requirements of detergent additives and anti-icing functionality. When combined with polyol ester, it allows detergent additives to maintain engine cleanliness while the overall additive system prevents ice flake formation, resolving the aggravation effect

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents ice flake formation in diesel fuels at low temperatures while maintaining engine cleanliness and reducing raw material costs, ensuring the fuel's performance and properties are preserved.

Implementation Method 1

This combination of additives surprisingly prevents the formation of ice flakes in a fuel at temperatures below or equal to -15°C, or even below or equal to -25°C, or even below or equal to -30°C

Methodology Applied
Scientific EffectFreezing point depression: Freezing

Data Source

PatentEP3529338B1Combination of additives for fuel
Publication Date: 2023.07.19 TOTALENERGIES ONETECH
  • EP3529338B1 patent drawing
  • EP3529338B1 patent drawing

AI summary

The invention relates to a fuel composition which comprises at least: a fuel from one or more sources selected from the group that comprises mineral, plant and synthetic sources; a compound (T1) selected among polyalkylene glycols, C1-C12 alkyl and polyalkylene glycol ethers, and the mixtures thereof; and a compound (T2) selected among the non-ionic emulsifiers. The invention also relates to an additive composition comprising at least: a compound (T1) selected among the C1-C6 alkyl and polyethylene glycol ethers comprising two to six units of ethylene glycol; a compound (T2) selected among the esters of one or more C1-C36 alkenyl carboxylic or alkyl carboxylic acids, and a polyol selected among sorbitan and isosorbide, taken alone or mixed together; and possibly a detergent additive. The invention further relates to a method for preventing, avoiding or delaying the formation of ice crystals or flakes in a tank of a vehicle provided with an internal combustion engine.