Fuel Additive Composition for Viscosity and Stability

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Solution Overview

Problem

The use of heavier, less refined fuels in engines is hindered by issues such as viscosity, sedimentation, and carbon deposition, which lead to efficiency losses and environmental concerns, while lighter fuels are more expensive and prone to instability during transportation and storage.

Innovation Solution

A fuel additive composition containing a metal compound like ferrocene, an organic compound like camphor, and a stabilizer such as an asphaltene dispersant is used to improve the viscosity and stability of fuels, reducing carbon formation and improving combustion efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If heavier, less refined fuels are used to reduce cost, then fuel cost decreases, but viscosity increases and combustion efficiency deteriorates

Engineering Contradiction:
Improvefuel costVSAvoidcombustion efficiency
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

Ferrocene acts as a catalytic intermediary that facilitates more complete combustion of heavier fuels. The metal compound (ferrocene) serves as a mediator between the fuel and combustion process, enabling efficient burning of fuels that would otherwise combust poorly, thus resolving the contradiction between using cheaper heavy fuel and maintaining combustion efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical parameters of the fuel system by introducing ferrocene and camphor additives. These additives modify the combustion characteristics and stability parameters of the fuel, allowing heavier fuels to achieve combustion efficiency comparable to lighter fuels while maintaining cost advantages

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If heavier fuels are used to reduce cost, then fuel cost decreases, but carbon deposition increases

Engineering Contradiction:
Improvefuel costVSAvoidcarbon deposition
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

Ferrocene serves as a catalytic intermediary that promotes complete combustion and prevents carbon deposition. The additive mediates the combustion process to ensure thorough oxidation of carbon-containing compounds, preventing them from depositing as soot or carbon on engine components while allowing use of cheaper heavy fuels

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention converts the potentially harmful unstable components in heavy fuel into beneficial effects. The ferrocene catalyst transforms what would be carbon-depositing compounds into fully combusted products, turning the harmful tendency of heavy fuel toward incomplete combustion into an opportunity for efficient, clean burning at lower cost

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Productivity

If lighter, more refined fuels are used to improve combustion efficiency, then combustion efficiency improves, but fuel cost increases

Engineering Contradiction:
Improvecombustion efficiencyVSAvoidfuel cost
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The ferrocene additive acts as a mediator that enables heavy fuel to achieve the combustion efficiency of light fuel without the associated cost penalty. By introducing this catalytic intermediary, the system obtains the benefits of efficient combustion while using the cheaper heavy fuel base stock

Inventive Principle:
Principle #24Intermediary (Mediator)

4Quantity of substance

If blended fuels are used to balance cost and performance, then fuel cost decreases, but stability deteriorates

Engineering Contradiction:
Improvefuel costVSAvoidfuel stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The stabilizer additive (such as phenolic compounds or amine-based stabilizers) acts as a mediator that prevents degradation and phase separation in blended fuels. It mediates between the different fuel components to maintain compositional stability during storage and handling, enabling use of cost-effective blended fuels without sacrificing stability

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The additive composition allows the use of heavier fuels by reducing viscosity and sedimentation, minimizing carbon deposition, and enhancing combustion efficiency, leading to cost savings and reduced environmental impact.

Implementation Method 1

Ferrocene and its derivatives as well as corresponding manufacturing procedures have been the object of numerous patents... an iron compound, especially ferrocene... which may act as a combustion catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

an organic compound selected from a bicyclic monoterpene, a substituted bicyclic monoterpene, adamantane, propylene carbonate and mixtures thereof... an organic compound like camphor

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 3

a stabiliser wherein (iii) comprises an asphaltene dispersant, a cold flow improver, a wax antisettling additive, or mixtures thereof... improving the stability of fuel which may otherwise suffer from stability problems, for example phase separation, or separation or aggregation of polyaromatic compounds within the fuel

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Data Source

PatentEP2102317B1Additive, fuel composition, method and use
Publication Date: 2018.10.17 INNOSPEC LTD
  • EP2102317B1 patent drawingFigure 1
  • EP2102317B1 patent drawing
  • EP2102317B1 patent drawing

AI summary

An additive composition for a fuel comprises: (i) a metal compound selected from an iron compound, a manganese compound, a calcium compound, a cerium compound and mixtures thereof; (ii) an organic compound selected from a bicyclic monoterpene, substituted bicyclic monoterpene, adamantane, propylene carbonate and mixtures thereof; and (iii) a stabiliser. The additive composition allows fuels which are prone to separation, for example blended fuels or fuels having a high content of asphaltenes, to be used successfully.