Fuel Cell Anode Bleed Control During Power Transients

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Solution Overview

Problem

In fuel cell systems, controlling hydrogen concentration during anode exhaust gas bleed is challenging, especially during power up-transients and cathode pulsing, as existing methods lack effective means to prevent hydrogen levels from exceeding safe limits without adding complexity or cost, such as using combustors or unreliable hydrogen sensors.

Innovation Solution

A fuel cell system that employs a by-pass valve to detect power up-transients and cathode pulsing by monitoring the rate of by-pass valve closure and compressor airflow set-point changes, pausing anode exhaust gas bleed during these events to prevent hydrogen concentration from exceeding safe limits, and resetting the bleed prevention time as needed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If anode exhaust gas bleed is performed to remove nitrogen from the anode side, then nitrogen concentration is reduced and stack stability is improved, but hydrogen concentration in exhaust gas may exceed safe limits during power up-transients and cathode pulsing

Engineering Contradiction:
Improvestack stabilityVSAvoidhydrogen concentration in exhaust gas
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The controller predicts power up-transients and cathode pulsing events before they occur by monitoring the rate of by-pass valve closure and compressor airflow set-point changes. When these events are predicted, the controller proactively prevents anode exhaust gas bleeding, thereby avoiding hydrogen concentration exceedance in the exhaust gas while maintaining stack stability through alternative nitrogen management strategies.

Inventive Principle:
Principle #10Preliminary action

2Object-affected harmful factors

If combustor is added to burn hydrogen in bled gas before exhaust, then hydrogen safety is improved, but system cost and complexity increase significantly

Engineering Contradiction:
Improvehydrogen safetyVSAvoidsystem complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

Instead of adding a combustor to handle hydrogen in the bled gas, the invention converts the potential harm into a benefit by using the existing cathode exhaust air flow to dilute and safely manage the hydrogen concentration. The controller monitors and predicts operating conditions to ensure hydrogen remains within safe limits, thereby eliminating the need for additional combustion equipment while maintaining safety.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-affected harmful factors

If hydrogen concentration sensor is used to monitor exhaust gas, then hydrogen safety control is improved, but system cost increases and sensor reliability in humid environment is reduced

Engineering Contradiction:
Improvehydrogen concentration controlVSAvoidsensor reliability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The controller implements a feedback mechanism that continuously monitors the rate of by-pass valve closure and compressor airflow set-point changes to predict power up-transients and cathode pulsing. This feedback loop enables the system to proactively adjust anode exhaust gas bleeding operations, maintaining hydrogen concentration within safe limits without requiring additional hydrogen concentration sensors in the exhaust stream.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively manages hydrogen concentration in the exhaust gas during power up-transients and cathode pulsing, preventing stack instability and reducing the risk of hydrogen accumulation, thereby enhancing safety and system reliability without adding significant cost or complexity.

Implementation Method 1

A fuel cell system that employs a by-pass valve to detect power up-transients and cathode pulsing by monitoring the rate of by-pass valve closure and compressor airflow set-point changes

Methodology Applied
Scientific EffectFlow rate monitoring:

Implementation Method 2

It is known in the art to provide a bleed valve to remove nitrogen from the anode side of the stack

Methodology Applied
Scientific EffectGas flow control:

Implementation Method 3

If the concentration of hydrogen was too high, the controller would increase the speed of the compressor to provide more cathode exhaust air to lower the concentration of hydrogen

Methodology Applied
Scientific EffectGas mixing and dilution:

Implementation Method 4

A hydrogen fuel cell is an electrochemical device that includes an anode and a cathode with an electrolyte therebetween. The anode receives hydrogen gas and the cathode receives oxygen or air. The hydrogen gas is dissociated in the anode to generate free protons and electrons

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Data Source

PatentUS7862941B2Hydrogen emissions control during up-transients and cathode pulsing
Publication Date: 2011.01.04 GM GLOBAL TECHNOLOGY OPERATIONS LLC
  • US7862941B2 patent drawing
  • US7862941B2 patent drawing

AI summary

A fuel cell system that controls an anode exhaust gas bleed during power up-transients. The fuel cell system includes a by-pass valve that allows compressor air to by-pass the fuel cell stack and be directly emitted into the cathode exhaust gas stream. The system detects a power up-transient by monitoring the rate of closing of the by-pass valve and the rate of change of an increase in the compressor airflow set-point. If these parameters pass a certain threshold, then the system determines that a power up-transient is occurring, and prevents an anode exhaust gas bleed for a predetermined period of time. If cathode pulsing is occurring where power up-transients come one after another, then the system will continuously reset the time period for preventing the anode exhaust gas bleed until a second time limit is reached, where the bleed is then forced.