Fuel Cell Anode Gas Concentration Control via Capacitance

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Solution Overview

Problem

Existing fuel cell systems cannot accurately detect the dry-out of the electrolyte membrane or a decrease in anode gas concentration due to the lack of consideration for anode gas concentration effects on combined capacitance, making it difficult to distinguish between wetness and gas concentration states.

Innovation Solution

A fuel cell system with a wetness control state determination unit, a combined capacitance calculation unit, and an anode gas concentration control unit that calculates and responds to changes in combined capacitance to detect and adjust anode gas concentration, separate from wetness control, ensuring proper operation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If the existing fuel cell system uses combined capacitance measurement for diagnosis, then the degree of wetness of electrolyte membrane can be detected, but the anode gas concentration cannot be distinguished from wetness state

Engineering Contradiction:
Improvedetection accuracy of electrolyte membrane wetnessVSAvoidinability to distinguish anode gas concentration state
Core Design Contradiction:
Measurement precisionVSLoss of information

Solution Approach 1:

The patent segments the diagnosis into two distinct modes: wetness diagnosis mode and anode gas concentration diagnosis mode. By separating the diagnostic functions and executing them at different times with different control conditions, the system can accurately detect each parameter without interference from the other, resolving the information loss problem.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent dynamically switches between different diagnostic modes based on operational conditions. The control unit selects wetness diagnosis mode or anode gas concentration diagnosis mode according to the current state, allowing the system to adaptively diagnose different parameters at appropriate times, thereby improving overall measurement precision while avoiding parameter confusion.

Inventive Principle:
Principle #15Dynamics

2Reliability

If the fuel cell system controls only wetness based on combined capacitance, then wetness maintenance is achieved, but anode gas concentration decrease cannot be detected or responded to

Engineering Contradiction:
Improvewetness control stabilityVSAvoidability to respond to anode gas concentration changes
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent makes the diagnosis system multi-functional by enabling it to perform both wetness diagnosis and anode gas concentration diagnosis using the same combined capacitance measurement capability. The control unit selectively activates different diagnostic functions based on operational needs, allowing a single system to handle multiple diagnostic tasks and respond to various operational states.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent changes the diagnostic parameters and control conditions based on the target parameter being measured. For wetness diagnosis, specific capacitance thresholds and control conditions are applied, while for anode gas concentration diagnosis, different thresholds and purge control strategies are used. This parameter adaptation enables the system to reliably control wetness while also detecting and responding to gas concentration changes.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If the system increases purge flow rate to maintain anode gas concentration, then gas concentration is improved, but electrolyte membrane may become excessively wet

Engineering Contradiction:
Improveanode gas concentrationVSAvoidwater content in electrolyte membrane
Core Design Contradiction:
Quantity of substanceVSLoss of substance

Solution Approach 1:

The patent implements feedback control by continuously monitoring combined capacitance values and adjusting purge flow rate accordingly. When anode gas concentration decreases, the system increases purge flow rate to restore concentration. When electrolyte membrane wetness becomes excessive, the system reduces purge flow rate to prevent over-humidification. This closed-loop feedback mechanism balances gas concentration maintenance with wetness control.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent applies preliminary anti-action by predicting and preventing adverse effects before they occur. The system monitors trends in combined capacitance values and adjusts purge flow rate in advance to prevent both gas concentration depletion and excessive wetness. By taking preventive action based on early detection of parameter changes, the system avoids the need for corrective actions that could cause opposite problems.

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables reliable detection and recovery of anode gas concentration, improving power generation efficiency by distinguishing between wetness and gas concentration states, preventing operational failures and maintaining efficient fuel cell performance.

Implementation Method 1

a fuel cell for generating electrical power upon being supplied with anode gas and cathode gas

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Implementation Method 2

a combined capacitance calculation unit configured to calculate a combined capacitance of the fuel cell

Methodology Applied
Scientific EffectCapacitance: Capacitance

Data Source

PatentUS10038207B2Fuel cell system
Publication Date: 2018.07.31 NISSAN MOTOR CO LTD
  • US10038207B2 patent drawing
  • US10038207B2 patent drawing
  • US10038207B2 patent drawing

AI summary

A fuel cell system includes a fuel cell for generating electrical power upon being supplied with anode gas and cathode gas. The fuel cell system includes a wetness control state determination unit that determines whether or not a wetness control of controlling a degree of wetness of an electrolyte membrane of the fuel cell is normally executed, a combined capacitance calculation unit that calculates a combined capacitance of the fuel cell, and an anode gas concentration control unit that determines the occurrence of decrease in an anode gas concentration in the fuel cell or executes a control for increasing the anode gas concentration if the combined capacitance of the fuel cell is smaller than a predetermined value when the wetness control is determined to be normally executed.