Fuel Cell Case Anodic Oxide Coating Corrosion

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Solution Overview

Problem

Fuel cell modules are prone to corrosion due to water remaining in crevices between the case and seal members, leading to potential damage and inefficiency.

Innovation Solution

The application of an anodic oxide coating with enhanced rust and wear resistance on surfaces of the case, particularly in areas where water tends to accumulate, such as grooves and press-fitting holes, along with sealing the coating to improve rust resistance and prevent adhesive friction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If water enters the crevice between the case and seal member, then the case is exposed to corrosion, but forming an anodic oxide coating on the case surface increases manufacturing complexity

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The anodic oxide coating is formed on the case surface before assembly with the seal member, creating a protective layer in advance that prevents corrosion when water enters the crevice. This preliminary protective action eliminates the need for complex post-assembly corrosion protection measures.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The case is formed as a composite structure combining aluminum base material with an anodic oxide coating layer. This composite material provides both the structural properties of aluminum and the enhanced corrosion resistance of the oxide coating, solving the reliability issue without requiring complex external protection systems.

Inventive Principle:
Principle #40Composite materials

2Weight of moving object

If aluminum or aluminum alloy is used for the case, then weight is reduced, but corrosion resistance is insufficient when water remains in crevices

Engineering Contradiction:
Improvecase weightVSAvoidcorrosion resistance
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The aluminum case is combined with an anodic oxide coating to create a composite material structure. The aluminum provides lightweight properties while the oxide coating provides enhanced corrosion resistance, simultaneously satisfying both weight reduction and reliability requirements.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The surface properties of the aluminum case are changed through anodizing, which transforms the surface chemistry and structure to create a more corrosion-resistant anodic oxide layer while maintaining the bulk aluminum's lightweight characteristics.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Effectively suppresses corrosion and prevents electric leakage by forming a durable, insulating barrier against water, enhancing the longevity and performance of the fuel cell module, especially when installed below a vehicle's floor where water splashing is likely.

Implementation Method 1

As a rust-proof treatment for aluminum or the aluminum alloy, the effect of an anodizing treatment is high. According to the above configuration, since the anodic oxide coating having rust resistance higher than those of aluminum and the aluminum alloy is formed on the surface

Methodology Applied
Scientific EffectAnodizing: Anodising

Implementation Method 2

since the anodic oxide coating having an insulating property higher than those of aluminum and the aluminum alloy is formed on the surface inside the case, in the case where the high-voltage portion comes into contact with the surface on which the anodic oxide coating is formed inside the case, it is possible to prevent an electric leakage from the high-voltage portion to the case

Methodology Applied
Scientific EffectElectrical insulation: Electrical Resistance

Data Source

PatentEP3018749B1Fuel cell module
Publication Date: 2020.03.04 TOYOTA JIDOSHA KK
  • EP3018749B1 patent drawingFigure 1
  • EP3018749B1 patent drawingFigure 2
  • EP3018749B1 patent drawingFigure 3

AI summary

A fuel cell module is disposed below a floor of a vehicle (10). The fuel cell module includes: a high-voltage portion including a fuel cell (110); a case (120) that is formed of aluminum or aluminum alloy and that accommodates at least a part of the high-voltage portion; and a gasket (160) sandwiched between the case (120) and another component (170), which is different from the case (120). An anodic oxide coating is formed on at least a surface that comes into contact with the gasket (160) in a surface of the case (120).