Fuel Cell Exhaust Condensate Sampling for Stable Ion Analysis

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Solution Overview

Problem

Conventional fuel cell evaluation systems face challenges in accurately measuring ion concentrations due to variations in moisture content and flow rate of exhaust gas, leading to reduced measurement accuracy and delayed reflection of fuel cell condition changes.

Innovation Solution

An ion analysis device with a sampling unit that collects condensate from a first reservoir in the exhaust gas line or samples exhaust gas to collect condensate in a second reservoir, ensuring a stable supply to the sensor unit, minimizing the impact of flow rate and moisture content variations, and including a gas-liquid separator to remove air bubbles and a temperature adjustment unit to maintain consistent conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a constant amount of condensate is collected in a reservoir provided to the exhaust gas line, then the ion concentration measurement can be performed, but the measurement accuracy is reduced due to variations in moisture content and flow rate of exhaust gas

Engineering Contradiction:
Improveion concentration measurement accuracyVSAvoidmeasurement stability under varying exhaust gas conditions
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The exhaust gas line is divided into multiple sampling points along its length. Instead of collecting condensate from a single reservoir, the system segments the exhaust gas flow and samples condensate from multiple locations, thereby obtaining a more representative and stable ion concentration measurement that is less affected by local variations in moisture content and flow rate.

Inventive Principle:
Principle #1Segmentation

2Quantity of substance

If condensate is collected from the entire exhaust gas flowing through the exhaust gas line, then the ion concentration can be measured, but the measurement is affected greatly by changes in flow rate or moisture content

Engineering Contradiction:
Improveamount of condensate collectedVSAvoidion concentration measurement accuracy
Core Design Contradiction:
Quantity of substanceVSMeasurement precision

Solution Approach 1:

Instead of measuring ion concentration from the entire condensate flow, the invention extracts a small, controlled sample of condensate from multiple sampling points along the exhaust gas line. This extracted sample is then concentrated and measured, thereby obtaining an accurate ion concentration reading that is not diluted by variations in the total condensate volume caused by changes in exhaust gas flow rate or moisture content.

Inventive Principle:
Principle #2Taking out (Extraction)

3Quantity of substance

If the reservoir fails to collect sufficient condensate due to low moisture content, then the ion concentration cannot be measured accurately, but adding more reservoir capacity causes temporary dilution when high moisture content exhaust gas is discharged

Engineering Contradiction:
Improvecondensate collection amountVSAvoidion concentration measurement accuracy
Core Design Contradiction:
Quantity of substanceVSMeasurement precision

Solution Approach 1:

Rather than using a single large reservoir that must accommodate all variations in condensate production, the invention employs multiple smaller sampling points distributed along the exhaust gas line. Each sampling point collects a small amount of condensate locally, and these samples are combined and concentrated. This approach ensures sufficient condensate is always available for measurement without causing dilution problems, because the system adapts to local condensate availability at each sampling point.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables more responsive and accurate evaluation of fuel cell conditions by stabilizing condensate supply and minimizing measurement inaccuracies caused by condensate shortages or fluctuations, allowing for timely reflection of fuel cell changes.

Implementation Method 1

a sampling unit configured to sample condensate of exhaust gas flowing through an exhaust gas line

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 2

a sensor unit configured to measure an ion concentration of the condensate

Methodology Applied
Scientific EffectIon concentration measurement:

Data Source

PatentUS20240387843A1Ion analysis device and fuel cell evaluation system
Publication Date: 2024.11.21 HORIBA LTD
  • US20240387843A1 patent drawing
  • US20240387843A1 patent drawing
  • US20240387843A1 patent drawing

AI summary

An ion analysis device includes a sampling unit configured to sample condensate of exhaust gas flowing through an exhaust gas line in a fuel cell; and a sensor unit configured to measure an ion concentration of the condensate, in which the sampling unit is configured to sample the condensate of the exhaust gas from a first reservoir that is provided to the exhaust gas line and where the condensate of the exhaust gas is collected, or to sample the exhaust gas from the exhaust gas line and to collect condensate of the sampled exhaust gas in a second reservoir.